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Synthesis and applications of the sulfur containing analogues of cyclic carbonates
Cyclic thiocarbonates are the sulfur containing analogues of the well-studied cyclic carbonates and are relatively poorly ...
Organic & Biomolecular Chemistry
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Chiral sulfide and selenide catalysts for asymmetric halocyclizations and related reactions
Asymmetric organocatalysis using well-designed artificial chiral molecular catalysts is one of the most reliable methods t...
Organic & Biomolecular Chemistry
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Chiral phosphoric acid-catalyzed Friedel-Crafts reaction of 2,5-disubstituted and 2-monosubstituted pyrroles with isoindolinone-derived ketimines
Enantioselective reaction between 2,5-disubstituted pyrroles and diaryl-ketimines, generated in situ from isoindolinone-de...
Organic & Biomolecular Chemistry
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A Structure Activity Relationship Study of 3,4’-Dimethoxyflavone for ArlRS Inhibition in Staphylococcus aureus
Infections caused by methicillin-resistant Staphylococcus aureus (MRSA) are difficult to treat due to their resistance to ...
Organic & Biomolecular Chemistry
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Kinetic resolution of sulfoxides with high enantioselectivity by a new homologue of methionine sulfoxide reductase B
Optically pure sulfoxides are noteworthy compounds that find wide applications in various industrial fields. Here we repor...
Organic & Biomolecular Chemistry
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Copper-catalyzed radical-mediated intermolecular cyanomonofluoroalkylation of alkenes and alkynes
A novel copper-catalyzed three-component reaction of monofluoroalkylation agents, alkenes and TMSCN is described. In addit...
Organic & Biomolecular Chemistry
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Deoxygenation of oximes for the synthesis of pyrrolines via hydroimination cyclization
Herein, we report the generation of iminyl radicals through photocatalytic deoxygenation of oximes with trivalent phosphin...
Organic & Biomolecular Chemistry
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Nickel-catalyzed reductive coupling of arylcarboxylic acid 2-pyridyl esters with alkyl methanesulfonates: access to alkyl aryl ketones
Alkyl aryl ketones were synthesized via nickel-catalyzed reductive coupling reaction of arylcarboxylic acid (2-pyridyl)est...
Organic & Biomolecular Chemistry
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Hydrogen Bond Directed High Fidelity Optical Detection of Picric Acid: Single Driver through Diverse Road towards Same Destiny
High-fidelity optical detection of picric acid is the urge of the time due to its toxic and explosive nature. Moreover, Pi...
Organic & Biomolecular Chemistry
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Synthesis, conformational stability and molecular structure of 4-aryl- and 4,5-diaryl-1,8-bis(dimethylamino)naphthalenes
4-Bromo- and 4,5-dibromo-1,8-bis(dimethylamino)naphthalenes were arylated with arylboronic acids under Suzuki reaction con...
Organic & Biomolecular Chemistry
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From Oximes to Tertiary Alcohols in Water, at Room Temperature in Air: Hybrid One-pot Tandem Assembly of Enzymatic Deoximation and RLi/RMgX Reagents
The highly efficient biodeoximation of aromatic ketoximes, promoted by the enzymatic oxidative system laccase/TEMPO/O2 has...
Organic & Biomolecular Chemistry
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Photocatalytic synthesis of azaheterocycle-fused piperidines and pyrrolidines via tandem difunctionalization of unactivated alkenes
A variety of azaheterocycle-fused piperidines and pyrrolidines bearing CF3 and CHF2 functionalities were achieved using CF...
Organic & Biomolecular Chemistry
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Correction: An asymmetric metal-templated route to amino acids with an isoquinolone core via a Rh(III)-catalyzed coupling of aryl hydroxamates with chiral propargylglycine Ni(II) complexes
Correction for ‘An asymmetric metal-templated route to amino acids with an isoquinolone core via a Rh(iii)-catalyzed coupl...
Organic & Biomolecular Chemistry
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Synthesis of Quinazolinones via Cp*Co(III)-Catalyzed C-H Functionalization of Primary Amides with Oxadiazolones
Multi-heteroatom heterocycle synthesis through direct C-H bond activation is methodologically appealing but synthetically ...
Organic & Biomolecular Chemistry
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Kinetic analysis for highly effective triplex formation between small molecule-peptide nucleic acid conjugate probe and Influenza A virus RNA promoter region at neutral pH
In order to overcome pH limitations of triplex-forming peptide nucleic acid (PNA) for the binding to double-stranded RNA (...
Organic & Biomolecular Chemistry
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Catalytic Aminomethylative Etherification of N-Allenamides with N,O-Acetals Enabled by Lewis/Brønsted Acid Catalysis
A novel copper-catalyzed aminomethylative etherification of N-allenamides/ alkoxyallenes with N,O-acetals have been realiz...
Organic & Biomolecular Chemistry
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Formal Synthesis of Cyclotheonellazole A
A convergent procedure for the formal synthesis of cyclotheonellazole A has been developed with high yields and excellent ...
Organic & Biomolecular Chemistry
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Cu(II)-catalyzed domino construction of spironaphthalenones by dearomatization of β-naphthols and using N, N-dimethylaminoethanol as a C1 synthon
Herein, a Cu(II)-catalyzed facile construction of synthetically valuable spiro compounds from β-Naphthols under air is rep...
Organic & Biomolecular Chemistry
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Modular Synthesis of Fluorinated 2H-Thiophenes via [4+1] Cyclization of Enaminothiones
An efficient and straightforward synthetic method has been disclosed to construct trifluoromethyl 2H-thiophenes through [4...
Organic & Biomolecular Chemistry
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Thia-Michael Addition: The Route to Promising Opportunities for Fast and Cysteine-Specific Modification
Over the last few decades, design and discovery of chemical reactions that enable modification of proteins at pre-determin...
Organic & Biomolecular Chemistry
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Correction: An efficient metal free synthesis of 2-aminobenzothiozoles – a greener approach
Correction for ‘An efficient metal free synthesis of 2-aminobenzothiozoles – a greener approach’ by Krithika Ganesh et al....
Organic & Biomolecular Chemistry
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Ru(II)-Catalyzed Oxidative Coupling of Sulfoxonium Ylides with Amines: Efficient Synthesis of α-Ketoamides and Indolo[2,1-a]isoquinolines
The first use of sulfoxonium ylides for the synthesis of α-ketoamides is described via Ru(II)-catalyzed amidation reaction...
Organic & Biomolecular Chemistry
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Defluorinative Alkylation of 1-Trifluoromethyl Alkenes with Alkyl Radicals Derived from Visible-Light Induced Deoxygenation of Xanthate Salts: Synthesis of gem-Difluoroalkenes
Catalyst- and metal-free difluoroallylation of alkyl precursors with trifluoromethyl alkenes for the synthesis of gem-difl...
Organic & Biomolecular Chemistry
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Nickel-Catalysed Enantioselective Reaction of Secondary Phosphine Oxides and Activated Vinylcyclopropanes
Activated vinylcyclopropanes (VCPs) can form zwitterionic π-allylmetal species in the presence of transition metals and ar...
Organic & Biomolecular Chemistry
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Stabilizing the hydroperoxyflavin intermediate formation via peptide appendage: A neutral flavoenzyme model
A bioinspired mimic for the stabilization of hydroperoxyflavin intermediate formation was designed and investigated for th...
Organic & Biomolecular Chemistry
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Synthesis of 1,2-diaminotruxinic δ-cyclobutanes by BF3-controlled [2+2]-photocycloaddition of 5(4H)-oxazolones. Stereoselective expansion of δ-cyclobutanes to give highly substituted pyrrolidine-2,5-dicarboxylates
The irradiation of (Z)-4-arylidene-5(4H)-oxazolones 1a-1u with blue light (465 nm) in presence of the photosensitizer [Ru(...
Organic & Biomolecular Chemistry
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Synthesis and Ring-Opening Metathesis Polymerisation of O-Alkoxy Benzothiadiazole Paracyclophane-1,9-dienes
Ortho-diethylhexyloxyphenylene benzothiadiazole paracyclophane-1,9-diene as a mixture of diastereomers was synthesized by ...
Organic & Biomolecular Chemistry
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Host-guest complexation of phthalimide-derived strigolactone mimics with cyclodextrins. Application in agriculture against parasitic weeds
Parasitic weeds are noxious plants that damage crops of economic relevance, especially in Mediterranean and African countr...
Organic & Biomolecular Chemistry
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Factors influencing on-resin depsipeptide bond formation: Case studies on daptomycin- and brevicidine-derived sequences
Depsipeptides are an important class of bioactive natural products, where a growing number of genome-mined structures that...
Organic & Biomolecular Chemistry
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Bimodal structural tuning of pyrrole-2-carboxamide-based transmembrane ion transport system
Pyrrole-2-carboxamide moiety is well known for its presence in various natural products and its use in anion receptor syst...
Organic & Biomolecular Chemistry
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