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A Benzofuran-[b]-Fused BODIPY Trimer Enabled by dual TBET and PET Mechanisms for High-Performance Two-Photon Fluorescence Imaging
A benzofuran-[b]-fused BODIPY trimer has been efficiently synthesized, featuring a unique structural design that harmoniou...
Ligand binding characteristics of an NAD+ riboswitch revealed by FRET and biolayer interferometry
The Class II NAD+ riboswitch is a bacterial RNA that binds ligands containing nicotinamide. Herein, we report a fluorescen...
Atroposelective Synthesis of Axially Chiral Indolizinylpyrroles by Catalytic Asymmetric Paal-Knorr Reaction
We present herein a highly efficient atroposelective synthesis of five/five-membered N-indolizinylpyrrole through the chir...
Large Scalable Nickel phosphide/Nickel@Carbon Cloth based Flexible Composite Electrodes for Symmetric Supercapacitors
A flexible Ni3P/Ni@CC composite electrode with remarkable mechanical robustness is developed by a scalable and facile synt...
Classification of self-assembled fluorescent probes and their application in cancer diagnosis
The high sensitivity, high selectivity, real-time monitoring capability, non-destructiveness, and versatility of small mol...
Orientation-modulated oxygen evolution reaction in epitaxial SrRuO3 films
The SrRuO3 films were grown on SrTiO3 using a lattice matching strategy. Scanning electrochemical microscopy imaged local ...
Bioinspired Metal-Organic Frameworks for Aqueous Environment Decontamination: From Laboratory Scale to Real-World Technologies.
Concerns regarding water contamination are escalating due to the increasing presence of all types of pollutants in water s...
From Boom to Bloom: Synthesis of Diazidodifluoromethane, its Stability and Applicability in the ‘Click’ Reaction
Diazidodifluoromethane was prepared from dibromodifluoromethane, sodium azide and an alkanethiolate initiator. It represen...
D5h H©Cu5H5-: a covalently bonded planar pentacoordinate hydrogen star
A D5h hydrocopper H©Cu5H5- star with planar pentacoordinate hydrogen (ppH) was designed. This structure is the global...
Rational Design of Water Splitting Electrocatalysts through Computational Insights
Electrocatalytic water splitting is vital for the sustainable production of green hydrogen. Electrocatalysts, including th...
Porous Crystalline Framework Materials Towards Direct Flue Gas Conversion
The photocatalytic direct conversion of carbon dioxide (CO2) from flue gas into high-value products is regarded as one of ...
Ni2+ mediated oxidation and aggregation of o-phenylenediamine: Enhanced photothermal effect for direct, specific and background-free detection of thiophanate-methyl
A novel photothermal probe, o-phenylenediamine trimer (triOPD)-Ni2+ aggregates with photothermal conversion efficiency up ...
Direct electrochemical N2 oxidation to nitrate on supportive Pt/CeO2
Here, we present the development of an efficient Pt/CeO2 catalyst for electrocatalytic N₂ oxidation to nitrate. Characteri...
Giant Molecule Acceptors Prepared by Metal-free Catalyzed Reactions towards Efficient Organic Solar Cells
Owing to the defined structure and large molecular size, giant molecular acceptors (GMAs) have exerted significant progres...
Ring Expansion of 3-Hydroxyoxindoles to 4-Quinolones via Palladium-Catalyzed C–C(acyl) Bond Cleavage and Subsequent Camps Cyclization
We report herein the construction of 4-quinolones via palladium-catalyzed regioselective β-acyl elimination of 3 hydroxyox...
SynAsk: Unleashing the Power of Large Language Models in Organic Synthesis
The field of natural language processing (NLP) has witnessed a transformative shift with the emergence of large language m...
Reactivity of Metal Hydrides with CO2: Going Beyond Formate with a High-Valent Cationic Pentahydride Mo(VI) Complex
The cationic molybdenum pentahydride complex [MoH5(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) is shown to undergo t...
Strongly Photoluminescent and Radioluminescent Copper(I) Iodide Hybrid Materials Made of Coordinated Ionic Chains
Scintillation-based X-ray detection has been widely used in various fields from medical diagnostics to security. In this s...
Structural Characterization of Surface Immobilized Platinum Hydrides by Sensitivity-Enhanced 195Pt Solid State NMR Spectroscopy and DFT Calculations
Supported single-site platinum hydride compounds are promising heterogeneous catalysts for organic transformations. Few me...
Effective Design Strategy for Thermally Activated Delayed Fluorescence Emitters with Aggregation-Induced emission to Enable Sky-blue OLEDs Achieving EQE Nearly 30%
Pure organic thermally activated delayed fluorescence (TADF) materials hold great promise for efficient organic light-emit...
Enantioselective Nickel-Catalyzed Electrochemical Reductive Conjugate Alkenylation of α,β-Unsaturated Ketones
Catalytic electrochemical asymmetric catalysis starting to emerg as a promising strategy for the synthesis of chiral compo...
Aluminium porphyrins catalyse the hydrogenation of CO2 withH2
Boron-based frustrated Lewis pairs (FLPs) have become well-established catalysts for the hydrogenation of a wide range of ...
Tandem Rh(II)-catalyzed 1,3-acyloxy migration/intermolecular [2+2] cycloaddition of electronically deficient propargylic esters with alkenes and alkynes
Transition metal-catalyzed 1,3-acyloxy migration of propargylic esters represents one of the most straightforward routes t...
Cobalt-tetraphenylporphyrin-based hypercrosslinked polymer for efficient CO2 photoreduction to CO
One of the main impediments during the CO2 photocatalytic reduction process is controlling a particular product’s selectiv...
Palladium-catalyzed Cascade Cyclization of Isocyanides with Di-(o-iodophenyl)sulfonylguanidines: Access to Heterocyclic Fused Quinazolines
A palladium-catalyzed cascade cyclization reaction of di-o-iodophenyl sulfonylguanidines with isocyanides for the efficien...
Effects of Dissolved 3d-block Metal Ions on PEM Water Electrolysis Performance
The influence of water impurities caused by 3d-block metal ion dissolution on proton exchange membrane (PEM) water electro...
Janus structural TaO/TaN heterojunction as efficient oxygen reduction electrocatalyst for H2O2 production
A Janus TaO/TaN heterojunction hybrid with graphene exhibited excellent activity, selectivity and durability for the 2e- o...
Spin Probe for Dynamics of the Internal Cluster in Endohedral Metallofullerenes
Endohedral metallofullerenes (EMFs) are constructed by fullerene cages encapsulating various metal atoms or metal clusters...
In-situ aniline polymerization during NH4V4O10 lattice formation achieve high-performance hybrid cathode for aqueous zinc-ion battery
Using NH4VO3 as both the precursor and oxidizing agent, polyaniline (PANI) is in-situ synthesized within NH4V4O10 (NVO) cr...
Visible-light-induced hydroalkylation of alkenes with aromatic β-ketoesters
A mild and environmentally friendly photocatalytic method for C-C bond formation between 1,3-dicarbonyls and styrene deriv...
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