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Advances and Challenges in Molecular Engineering of 2D/3D Perovskite Heterostructures
Organic-inorganic hybrid perovskite have been intensively studied in the past decades due to their outstanding performance...
A review on oxime functionality: An ordinary functional group with significant impacts in Supramolecular Chemistry
The oxime functional group is pivotal in chemistry, finding extensive applications in medical science, catalysis, organic ...
Mixing and Matching N,N- and N,O-Chelates in Anionic Mg(I) Compounds: Synthesis and Reactivity with RN=C=NR and CO
Reduction of [Mg(NON)]2 ([NON]2– = [O(SiMe2NDipp)2]2–, Dipp = 2,6-iPr2C6H3) affords Mg(I) species containing NON- and NNO-...
Asymmetric dearomatization of benzyl 1-naphthyl ethers via [1,3] O-to-C rearrangement
A catalytic asymmetric dearomatization reaction of benzyl 1-naphthyl ethers accelerated by a chiral N,Nʹ-dioxide/Co(II) co...
Spin polarization strategy regulates heterogeneous catalytic activity performance: from fundamental to application
In recent years, there has been significant attention towards the development of catalysts that exhibit superior performan...
2D Metal-Organic Frameworks Bearing Butterfly-shaped Metal-bis(dithiolene) Linkers from Dithiol-functionalized Benzenedicarboxylic Acid
Assembly between 1,4-dicarboxylbenzene-2,3-dithiol (H2dcbdt) and transition metal ions successfully produced 2D metal-orga...
Electro-catalytic water-to-oxygenates conversion: redox-mediated versus direct oxygen transfer
Electro-catalytic oxygenation of hydrocarbons with high selectivity has attracted much attention for its advantages of sus...
3D hierarchical Ti3C2/TiO2 composite via in situ oxidation for improved lithium-ion storage
To address the intrinsic limitations of both TiO2 and MXenes, we propose an effective strategy for the engineering of a 3D...
Oxidation mechanism of phenols by copper(II)-halide complexes
Oxidation mechanism of phenols by tetrahedral copper(II)-halide complexes was investigated to demonstrate that phenols hav...
Self-reporting Intracellular Delivery Agent for Singlet Oxygen
1,4-dimethylphenazine endoperoxide releases singlet oxygen with a half-life of 89 hours at 37 oC. The thermal cycloreversi...
Halogen Bonding Aza-BODIPYs for Anion Sensing and Anion Binding-Modulated Singlet Oxygen Generation
Two novel aza-BODIPY based anion sensors, decorated with halogen bonding recognition sites, are capable of detecting halid...
Amplification of Negative Gas Adsorption in a multivariate framework
The approach of multivariate MOFs was used to fine-tune the mechanical properties of the flexible framework DUT-49. In sit...
Sensitive subcellular scale and real-time detection of hydrogen peroxide by W-doped Pt microelectrode
Real-time detection of hydrogen peroxide (H2O2) in a subcellular scale is of importance for clinical diagnosis and physiop...
Visible-light-induced Ritter-type amidation of α-hydroxy ketones in the selectively synthesis of α,α-diamido and monoamido ketones
A visible light induced, transition metal-free oxidative dehydroxylation and C-H amidation of α-hydroxy ketones involving ...
Intermediates involved in the Reduction of SO2: Insight into the mechanism of Sulfite Reductases
Sulfite Reductase (SiR) catalyze the reduction of SO32- to H2S in both biosynthetic sulfur assimilation and dissimilation ...
Synthesis and Application of Well-Defined [Ph4P]+[Cu(CF2CF3)2]- Complex as a Versatile Pentafluoroethylating Reagent
We herein describe the preparation and application of a new bispentafluoroethylated organocuprate [Ph4P]+[Cu(CF2CF3)2]-. T...
Electroreductive Deuteroarylation of Alkenes Enabled by an Organo-Mediator
Electroreduction mediated by organo-mediators has emerged as a concise and effective strategy, holding significant potenti...
Regulation of microtubule dynamics and function in living cells via cucurbit[7]uril host-guest assembly
Living systems utilize sophisticated biochemical regulators and various signal transduction mechanisms to program bio-mole...
Multi-Electron Redox Reactivity of Samarium(II) Hydrido Complex
Well-defined low-valent molecular rare-earth metal hydrides are rare, and limited to Yb2+ and Eu2+ centers. Here, we repor...
Enantioselective Synthesis of C3-Functionalized 2,1-Benzothiazine 2,2-Dioxides by N-Heterocyclic Carbene Catalysis
We present herein an approach for the enantioselective C3-functionalization of 2,1-benzothiazine 2,2-dioxides using N-hete...
Influence of the substituents of thiol ligand on the optical properties of AuCu14
Detailed photophysical processes of two AuCu14 clusters with different substituents (-F or -C(CH3)3) of thiol ligand were ...
AI-Assisted Chemistry Research: A Comprehensive Analysis of Evolutionary Paths and Hotspots through Knowledge Graphs
Artificial intelligence (AI) offers transformative potential for chemical research through its ability to optimize reactio...
Length dependent reversible off-on activation of photo-switchable relay anion transporters
A homologous series of azobenzene-derived photo-switchable ion relay transporters is reported. We reveal that both the len...
Selective electrochemical nitrogen fixation to ammonia catalyzed by novel microporous vanadium phosphonate via distal pathway
Herein, a microporous organic-inorganic hybrid, vanadium phosphonate (VPn) material has been developed. With the combined ...
Electrochemical Synthesis of Phosphorylated Azaspiro[4.5]di/trienones through Dearomative Spirocyclization
Cp2Fe-mediated electrochemical synthesis of a diverse array of phosphorylated azaspiro[4.5]di/trienones has been developed...
Synthesis of Unsymmetrical Dialkoxydiarylsilanes and Diarylsilanediols from Tetraalkoxysilane Having a Dioxasilepane Unit
The tetraalkoxysilane carrying a stable seven-membered dioxasilepane moiety and two trifluoroethoxy groups undergoes relia...