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Isolation and characterization of a triplet nitrene
Isolation and characterization of a triplet nitrene
Nitrene radical compounds are short-lived intermediates in a variety of nitrogen-involved transformations. They feature ei...
Catalysis-enabled amine sorting
Catalysis-enabled amine sorting
Multicomponent couplings offer powerful approaches for rapidly increasing molecular complexity, but typically require func...
Dynamic amine sorting enables multiselective construction of unsymmetrical chiral diamines
Dynamic amine sorting enables multiselective construction of unsymmetrical chiral diamines
Precisely differentiating chemicals featuring minor discrepancies is the prerequisite for achieving high selectivities in ...
Light-assisted functionalization of aryl radicals towards metal-free cross-coupling
Light-assisted functionalization of aryl radicals towards metal-free cross-coupling
The many synthetic possibilities that arise when using radical intermediates, in place of their polar counterparts, make c...
A career with an eye to the sky
A career with an eye to the sky
Ahead of his 75th birthday, A. R. (Ravi) Ravishankara, Professor in the Departments of Chemistry and Atmospheric Science a...
Pore configuration control in hybrid azolate ultra-microporous frameworks for sieving propylene from propane
Pore configuration control in hybrid azolate ultra-microporous frameworks for sieving propylene from propane
Developing porous adsorbents for the complete sieving of propylene/propane mixtures represents an alternative method to en...
Cracking the triple helix
Cracking the triple helix
A novel method to detect proteins interacting with triplex DNA in living cells has been developed. This approach provides ...
Presenting the tactile periodic table
Presenting the tactile periodic table
Through the collaboration of two members of the ACS Committee on Chemists with Disabilities, a prototype Braille periodic ...
Mixing metals with MXenes
Mixing metals with MXenes
Metal/MXene composites are a combination of metals with highly conductive MXenes that results in an enhanced functionality...
Low-energy photoredox catalysis
Low-energy photoredox catalysis
With the advent of photoredox catalysis, new synthetic paradigms have been established with many novel transformations bei...
On-Site Analysis and Rapid Authentication of Valuable Agarwood Samples by Paper Capillary Spray Miniature Mass Spectrometry
On-Site Analysis and Rapid Authentication of Valuable Agarwood Samples by Paper Capillary Spray Miniature Mass Spectrometry
Agarwood is a resinous wood produced by plants of the genus Aquilaria in the Thymelaeaceae family after being injured. The...
Molecular-scale dissipative chemistry drives the formation of nanoscale assemblies and their macroscale transport
Molecular-scale dissipative chemistry drives the formation of nanoscale assemblies and their macroscale transport
Fuelled chemical systems have considerable functional potential that remains largely unexplored. Here we report an approac...
Exploring the boundaries of covalency
Exploring the boundaries of covalency
One electron σ-bonds were first proposed in 1931 but most discussion since then has been at a theoretical level. The ...
Smart molecular designs and applications of activatable organic photosensitizers
Smart molecular designs and applications of activatable organic photosensitizers
Photodynamic therapy (PDT) — which combines light, oxygen and photosensitizers (PS) to generate reactive oxygen spec...
Spatiotemporal protein interactome profiling through condensation-enhanced photocrosslinking
Spatiotemporal protein interactome profiling through condensation-enhanced photocrosslinking
Resolving protein–protein interactions (PPIs) inside biomolecular condensates is crucial for elucidating their funct...