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Inverse Opal‐Structured Sn and Sn/Ge Films from Soluble Zintl Clusters as Precursors
Inverse Opal‐Structured Sn and Sn/Ge Films from Soluble Zintl Clusters as Precursors
Tin and mixed tin/germanium thin films hold great potential for a variety of different applications such as anodes for lit...
Front Cover: (Z. Anorg. Allg. Chem. 1/2022)
Front Cover: (Z. Anorg. Allg. Chem. 1/2022)
ZAAC is an international scientific journal which publishes original papers on new relevant research results from all...
Celebrating 130 Years of ZAAC
Celebrating 130 Years of ZAAC
This year marks the 130th anniversary of ZAAC. It is incredible how chemistry has advanced as a discipline during this per...
Rapid adsorption and selective capture of methylene blue by anionic In‐based MOF with carboxyl‐decorated pore surface
Rapid adsorption and selective capture of methylene blue by anionic In‐based MOF with carboxyl‐decorated pore surface
We reported a PtS-type anionic metal organic framework (MOF) with uncoordinated carboxyl-groups and suitable pore size, (M...
Elucidating structural patterns in hydrogen bond dense materials: a study of ammonium salts of (4‐aminium‐1‐hydroxybutylidine)‐1,1‐bisphosphonic acid.
Elucidating structural patterns in hydrogen bond dense materials: a study of ammonium salts of (4‐aminium‐1‐hydroxybutylidine)‐1,1‐bisphosphonic acid.
Abstract The syntheses and structures of ammonium salts of the active pharmaceutical agent (4-aminium-1-hydroxybutylidine)...
Synthesis, Structures, and Properties of a Series of Isostructural Lanthanide‐Thiopheneacrylate Complexes
Synthesis, Structures, and Properties of a Series of Isostructural Lanthanide‐Thiopheneacrylate Complexes
Abstract We report the synthesis, crystal structures, and properties of three lanthanide(III) coordination complexes based...
A Novel Zn (II)‐Based Metal‐Organic Framework as a High Selective and Sensitive LuminescentSensor for the Detection of Nitrofuran Antibiotics
A Novel Zn (II)‐Based Metal‐Organic Framework as a High Selective and Sensitive LuminescentSensor for the Detection of Nitrofuran Antibiotics
The abuse of antibiotics has led to serious environmental and health problems in the modern society. The detection on anti...
Tuning topological networks in MOFs by secondary‐building‐unit connection: syntheses, structures and luminescent properties of two Zn4‐cluster coordination polymers
Tuning topological networks in MOFs by secondary‐building‐unit connection: syntheses, structures and luminescent properties of two Zn4‐cluster coordination polymers
Abstract Two new MOFs with a Zn4 SBU, namely 2 (I) and 2 ⋅ (H2O) (II), have been prepared through alt...
ARTICLE The Gallate Pnictides Ba9[GaO4]3Pn (Pn=Sb, Bi) and a Partially Oxidized Zintl Anion in Ba2[GaO­2As]
ARTICLE The Gallate Pnictides Ba9[GaO4]3Pn (Pn=Sb, Bi) and a Partially Oxidized Zintl Anion in Ba2[GaO­2As]
The reaction of elemental barium, gallium and either bismuth or antimony with small amounts of barium peroxide yields yell...
Syntheses, Structures and Cytotoxicity of Cu(II) Complexes with α‐Amino acid derived Benzamidines
Syntheses, Structures and Cytotoxicity of Cu(II) Complexes with α‐Amino acid derived Benzamidines
N -(diethylthiocarbamoyl)benzimidoyl chloride reacts with methyl esters of glycine, L-alanine, L-valine under formation of...
Hexanuclear Niobium Cluster Iodides with Pyridine Ligands – Temperature Induced Auto‐Oxidation
Hexanuclear Niobium Cluster Iodides with Pyridine Ligands – Temperature Induced Auto‐Oxidation
The cluster compounds [Nb6I8Py6] and [Nb6I8Py6]I·9Py, both with octahedral Nb6 metal atom cores were obtained from th...
Lutetium‐rich phases with a coloring variant of the Y3Rh2 type structure
Lutetium‐rich phases with a coloring variant of the Y3Rh2 type structure
The lutetium-rich intermetallic compounds Lu21T14– x In x (T = Rh, Pd, Pt) with x values ranging from 1.57 to 4.70 ...
Half antiperovskites VII – DFT modelling of shandites that are isoelectronic to Co3Sn2S2
Half antiperovskites VII – DFT modelling of shandites that are isoelectronic to Co3Sn2S2
Our discovery of half metal ferromagnetic (HFM) properties on shandite type Co 3 Sn 2 S 2 = Sn 2 Co 3 S 2 about 20 years a...
NHC‐Stabilized Parent Phosphinidene Adducts of Metal(II) Hexamethyldisilazanides of Manganese – Cobalt and Their Lability in Solution
NHC‐Stabilized Parent Phosphinidene Adducts of Metal(II) Hexamethyldisilazanides of Manganese – Cobalt and Their Lability in Solution
The behavior of the N -heterocyclic carbene (NHC) stabilized ‘parent’ phosphinidene [(sIDipp)PH] (Dipp ...
A Symmetric F−H−F Hydrogen Bond in Strontium Bifluoride, Sr[HF2]2
A Symmetric F−H−F Hydrogen Bond in Strontium Bifluoride, Sr[HF2]2
Single crystal X-ray diffraction shows the hydrogen bond within the [F−H−F]− anion of Sr[HF2]2 to be ...
A metal‐organic framework ZJU‐136‐Ce for combined chemotherapy and chemodynamic therapy
A metal‐organic framework ZJU‐136‐Ce for combined chemotherapy and chemodynamic therapy
A metal-organic framework ZJU-136-Ce with ideal water stability was synthesized. It was adopted to load Mn 2+ and DOX for ...
Ag2VO2PO4 Nanorods: Synthesis, Characterization, Photoactivity and Antibacterial activity
Ag2VO2PO4 Nanorods: Synthesis, Characterization, Photoactivity and Antibacterial activity
Abstract Silver-containing materials have been the source of attraction due to their excellent optical and photocatalytic ...
Front Cover: (Z. Anorg. Allg. Chem. 23‐24/2021)
Front Cover: (Z. Anorg. Allg. Chem. 23‐24/2021)
ZAAC is an international scientific journal which publishes original papers on new relevant research results from all...
An Improved Synthesis of Bromotetrazole
An Improved Synthesis of Bromotetrazole
Abstract A new efficient synthesis of 5-bromotetrazole is presented. The free acid bromotetrazole was synthesized in a str...
[{TcI(NO)(LOMe)(PPh3)Cl}2Ag](PF6) and [TcII(NO)(LOMe)(PPh3)Cl](PF6): Two Unusual Technetium Complexes with a “Kläui‐type” Ligand
[{TcI(NO)(LOMe)(PPh3)Cl}2Ag](PF6) and [TcII(NO)(LOMe)(PPh3)Cl](PF6): Two Unusual Technetium Complexes with a “Kläui‐type” Ligand
The reaction of [Tc I (NO)(L OMe )(PPh 3 )Cl] ( - = η 5 -cyclo­pentadienyltris(dimethyl phosphito- P )cobaltate...
One‐pot synthesis of ICG&Cur@ZIF‐8 nanocomposites with pH‐controlled drug delivery and good photothermal performance
One‐pot synthesis of ICG&Cur@ZIF‐8 nanocomposites with pH‐controlled drug delivery and good photothermal performance
Abstract Combination therapy has shown great potential for effective cancer treatment. In this work, anticancer drug curcu...
A Solvate‐Isolated Linear Trimer CuNd2(CCl3COO)8 ⋅ 6MeCN: Structure, Synthesis and Magnetic Behavior
A Solvate‐Isolated Linear Trimer CuNd2(CCl3COO)8 ⋅ 6MeCN: Structure, Synthesis and Magnetic Behavior
Abstract A heterometallic copper-neodymium complex CuNd2(CCl3COO)8 ⋅ 6MeCN (1) was synthesized from a...
Synthesis, Crystal Growth, Electronic Properties and Optical Properties of Y6IV2.5S14 (IV=Si, Ge)
Synthesis, Crystal Growth, Electronic Properties and Optical Properties of Y6IV2.5S14 (IV=Si, Ge)
Two isostructural ternary acentric sulfides, Y 6 Si 2.5 S 14 ( 1 ) and Y 6 Ge 2.5 S 14 ( 2 ) were re-investigated to under...
Anti‐migration of Nitrogen‐rich N‐Heterocyclic Ferrocenes and Their Combustion Catalytic Properties in the Thermal Decomposition of Energetic Oxidizers
Anti‐migration of Nitrogen‐rich N‐Heterocyclic Ferrocenes and Their Combustion Catalytic Properties in the Thermal Decomposition of Energetic Oxidizers
To retard high migration tendency of alkylferrocene-based burning rate catalysts and ameliorate their combustion catalytic...
Post‐synthesis metal‐organic framework for turn‐on ratiometric fluorescence sensing of UO22+
Post‐synthesis metal‐organic framework for turn‐on ratiometric fluorescence sensing of UO22+
Abstract Uranium is an important and toxic radioactive nuclide, which is usually exist in nature water as uranyl ions. In ...
Two Intermediates in Ammonothermal InN Crystal Growth: [In(NH3)5Cl]Cl2 and InF2(NH2)
Two Intermediates in Ammonothermal InN Crystal Growth: [In(NH3)5Cl]Cl2 and InF2(NH2)
Abstract The ammonothermal synthesis is a promising instrument for synthesis and crystal growth of the metastable semicond...
Nickel Complexes of 2,3,5,6‐tetra‐(2‐pyridyl)pyrazine Containing [Ln(NO3)5]2− [Ln(III)=Nd, Eu, Gd, Tb, Dy, Er] as Counterions‐Syntheses, Structures and Luminescent Properties
Nickel Complexes of 2,3,5,6‐tetra‐(2‐pyridyl)pyrazine Containing [Ln(NO3)5]2− [Ln(III)=Nd, Eu, Gd, Tb, Dy, Er] as Counterions‐Syntheses, Structures and Luminescent Properties
Abstract Solvothermal reaction of [Ni(tppz)2](NO3)2 with Ln(NO3)3 ⋅ 6H2O afforded a 3d–4f hete...
A Terbium‐Based MOF as fluorescent probe for the detection of Malachite Green, Fe3+ and MnO4－
A Terbium‐Based MOF as fluorescent probe for the detection of Malachite Green, Fe3+ and MnO4－
Lanthanide MOFs (Ln-MOFs) have been widely used in biological imaging and fluorescence detection due to their remarkable o...
Electrochemical Synthesis of Graphene from Waste Discharged Battery Electrodes and Its Applications to Preparation of Graphene/Fe3O4/Chitosan‐Nanosorbent for Organic Dyes Removal
Electrochemical Synthesis of Graphene from Waste Discharged Battery Electrodes and Its Applications to Preparation of Graphene/Fe3O4/Chitosan‐Nanosorbent for Organic Dyes Removal
In this work, graphene was synthesized from waste discharged battery electrodes using an electrochemical exfoliation metho...
Lu20Ir5In3 and Lu20Pt5In3 – superstructures of the Al5Co2 type by coloring and distortion
Lu20Ir5In3 and Lu20Pt5In3 – superstructures of the Al5Co2 type by coloring and distortion
The lutetium-rich intermetallic compounds Lu 20 Ir 5 In 3 and Lu 20 Pt 5 In 3 were synthesized from the elements in sealed...
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