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Author Correction: Circumventing the stability problems of graphene nanoribbon zigzag edges
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which...
Publisher Correction: Photocatalytic hydrofluoroalkylation of alkenes with carboxylic acids
Author notesThese authors contributed equally: Kang-Jie Bian, Yen-Chu Lu.Authors and AffiliationsDepartment of Chemistry, ...
Enabling late-stage drug diversification by high-throughput experimentation with geometric deep learning
Enabling late-stage drug diversification by high-throughput experimentation with geometric deep learning
Late-stage functionalization is an economical approach to optimize the properties of drug candidates. However, the chemica...
A general strategy to develop fluorogenic polymethine dyes for bioimaging
A general strategy to develop fluorogenic polymethine dyes for bioimaging
Fluorescence imaging is an invaluable tool to study biological processes and further progress depends on the development o...
Publisher Correction: Droplet slipperiness despite surface heterogeneity at molecular scale
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which...
Phase-separation behaviour of RNAs
Phase-separation behaviour of RNAs
Ribonucleoprotein granules are ubiquitous in living organisms with the protein and RNA components having distinct roles. I...
Masked alkynes for synthesis of threaded carbon chains
Masked alkynes for synthesis of threaded carbon chains
Polyynes are chains of sp1 carbon atoms with alternating single and triple bonds. As they become longer, they evolve towar...
Remote stereocontrol with azaarenes via enzymatic hydrogen atom transfer
Remote stereocontrol with azaarenes via enzymatic hydrogen atom transfer
Strategies for achieving asymmetric catalysis with azaarenes have traditionally fallen short of accomplishing remote stere...
Modular and diverse synthesis of amino acids via asymmetric decarboxylative protonation of aminomalonic acids
Modular and diverse synthesis of amino acids via asymmetric decarboxylative protonation of aminomalonic acids
Stereoselective protonation is a challenge in asymmetric catalysis. The small size and high rate of transfer of protons me...
A 21-electron cobalt sandwich
A 21-electron cobalt sandwich
Now, Takebayashi, Gellrich, Fayzullin and co-workers have reported a 21-electron cobaltocene derivative Co(CpNCp) (picture...
RNAs undergo phase transitions with lower critical solution temperatures
RNAs undergo phase transitions with lower critical solution temperatures
Co-phase separation of RNAs and RNA-binding proteins drives the biogenesis of ribonucleoprotein granules. RNAs can also un...
Superstructural ordering in self-sorting coacervate-based protocell networks
Superstructural ordering in self-sorting coacervate-based protocell networks
Bottom-up assembly of higher-order cytomimetic systems capable of coordinated physical behaviours, collective chemical sig...
Discovery and synthesis of atropisomerically chiral acyl-substituted stable vinyl sulfoxonium ylides
Discovery and synthesis of atropisomerically chiral acyl-substituted stable vinyl sulfoxonium ylides
Atropisomerism is a type of conformational chirality that plays a critical role in various fields of chemistry, including ...
Optical sequencing of single synthetic polymers
Optical sequencing of single synthetic polymers
Microscopic sequences of synthetic polymers play crucial roles in the polymer properties, but are generally unknown and in...
Structure and bonding of a radium coordination compound in the solid state
Structure and bonding of a radium coordination compound in the solid state
The structure and bonding of radium (Ra) is poorly understood because of challenges arising from its scarcity and radioact...
In vitro selection of covalent aptamers with sulfur(VI) fluoride exchange chemistry
In vitro selection of covalent aptamers with sulfur(VI) fluoride exchange chemistry
To develop covalent inhibitors with high potency and low off-target effects, combinatorial approaches that search for cand...
Photocatalytic hydrofluoroalkylation of alkenes with carboxylic acids
Photocatalytic hydrofluoroalkylation of alkenes with carboxylic acids
Incorporation of fluoroalkyl motifs in pharmaceuticals can enhance the therapeutic profiles of the parent molecules. The h...
Regioselective, catalytic 1,1-difluorination of enynes
Regioselective, catalytic 1,1-difluorination of enynes
Fluorinated small molecules are prevalent across the functional small-molecule spectrum, but the scarcity of naturally occ...
Stereocontrolled access to thioisosteres of nucleoside di- and triphosphates
Stereocontrolled access to thioisosteres of nucleoside di- and triphosphates
Nucleoside diphosphates and triphosphates impact nearly every aspect of biochemistry; however, the use of such compounds a...
Electrolyte type affects electrochemical bubble formation
Electrolyte type affects electrochemical bubble formation
Gas bubble accumulation at interfaces is a barrier to achieving more efficient electrochemical devices. A clever model sys...
Using spatial and logical-mathematical intelligence for information wayfinding
Using spatial and logical-mathematical intelligence for information wayfinding
In the third of a trilogy of essays on types of intelligence, Bruce Gibb mines the thoughts of some of his peers on what p...
Droplet slipperiness despite surface heterogeneity at molecular scale
Droplet slipperiness despite surface heterogeneity at molecular scale
Friction determines whether liquid droplets slide off a solid surface or stick to it. Surface heterogeneity is generally a...
Programmable late-stage functionalization of bridge-substituted bicyclo[1.1.1]pentane bis-boronates
Programmable late-stage functionalization of bridge-substituted bicyclo[1.1.1]pentane bis-boronates
Modular functionalization enables versatile exploration of chemical space and has been broadly applied in structure–...
Entropy-driven charge-transfer complexation yields thermally activated delayed fluorescence and highly efficient OLEDs
Entropy-driven charge-transfer complexation yields thermally activated delayed fluorescence and highly efficient OLEDs
Exciplex-forming systems that display thermally activated delayed fluorescence are widely used for fabricating organic lig...
Heteromultivalency enables enhanced detection of nucleic acid mutations
Heteromultivalency enables enhanced detection of nucleic acid mutations
Detecting genetic mutations such as single nucleotide polymorphisms (SNPs) is necessary to prescribe effective cancer ther...
Rigid macrocycles with multiple hydrogen-bond donors for effective anion binding and transport
Rigid macrocycles with multiple hydrogen-bond donors for effective anion binding and transport
Aromatic oligoamide macrocycles have been developed in which the constrained backbone enforces hydrogen-bond donors to ori...
Aromatic pentaamide macrocycles bind anions with high affinity for transport across biomembranes
Aromatic pentaamide macrocycles bind anions with high affinity for transport across biomembranes
The convergent positioning of functional groups in biomacromolecules leads to good binding, catalytic and transport capabi...
Modular synthesis of 1,2-azaborines via ring-opening BN-isostere benzannulation
Modular synthesis of 1,2-azaborines via ring-opening BN-isostere benzannulation
1,2-Azaborines represent a unique class of benzene isosteres that have attracted interest for developing pharmaceuticals w...
Tetrafluorenofulvalene as a sterically frustrated open-shell alkene
Tetrafluorenofulvalene as a sterically frustrated open-shell alkene
Electronic and steric effects are known to greatly influence the structure, characteristics and reactivity of organic comp...
Casting TNT as an explosive
Casting TNT as an explosive
Few explosives are better-known to non-chemists than trinitrotoluene (TNT). Thomas M. Klapötke reflects on the enduri...
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