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Excitation energy transfer and vibronic coherence in intact phycobilisomes
Excitation energy transfer and vibronic coherence in intact phycobilisomes
The phycobilisome is an oligomeric chromoprotein complex that serves as the principal mid-visible light-harvesting system ...
Synthesis and single-molecule imaging reveal stereospecific enhancement of binding kinetics by the antitumour eEF1A antagonist SR-A3
Synthesis and single-molecule imaging reveal stereospecific enhancement of binding kinetics by the antitumour eEF1A antagonist SR-A3
Ternatin-family cyclic peptides inhibit protein synthesis by targeting the eukaryotic elongation factor-1α. A potenti...
Publisher Correction: Scalable and continuous access to pure cyclic polymers enabled by ‘quarantined’ heterogeneous catalysts
In the version of this article originally published, there was an error in the affiliation for Robert Tuba (Institute of M...
Bringing redox organics back to life
Bringing redox organics back to life
Aqueous organic redox flow batteries are promising for low-cost and large-scale energy storage, but the redox-active molec...
Multiphase model membraneless organelles
Multiphase model membraneless organelles
Quantitatively studying the partitioning of biomolecules and reaction equilibria in cellular systems is an enormous challe...
Nanopore microscope identifies RNA isoforms with structural colours
Nanopore microscope identifies RNA isoforms with structural colours
Identifying RNA transcript isoforms requires intricate protocols that suffer from various enzymatic biases. Here we design...
Structure, reactivity and catalytic properties of manganese-hydride amidate complexes
Structure, reactivity and catalytic properties of manganese-hydride amidate complexes
The high efficiency of widely applied Noyori-type hydrogenation catalysts arises from the N–H moiety coordinated to ...
Back to basics
Back to basics
Amines with free N–H groups have long posed a tremendous challenge in transition metal-catalysed amination reactions...
Polyoxometalates as ligands to synthesize, isolate and characterize compounds of rare isotopes on the microgram scale
Polyoxometalates as ligands to synthesize, isolate and characterize compounds of rare isotopes on the microgram scale
The synthesis and study of radioactive compounds are both inherently limited by their toxicity, cost and isotope scarcity....
Palladium-catalysed selective oxidative amination of olefins with Lewis basic amines
Palladium-catalysed selective oxidative amination of olefins with Lewis basic amines
Amines are prominent in natural products, pharmaceutical agents and agrochemicals. Moreover, they are synthetically valuab...
Lewis acid-assisted reduction of nitrite to nitric and nitrous oxides via the elusive nitrite radical dianion
Lewis acid-assisted reduction of nitrite to nitric and nitrous oxides via the elusive nitrite radical dianion
Reduction of nitrite anions (NO2−) to nitric oxide (NO), nitrous oxide (N2O) and ultimately dinitrogen (N2) takes pl...
Genome-based discovery and total synthesis of janustatins, potent cytotoxins from a plant-associated bacterium
Genome-based discovery and total synthesis of janustatins, potent cytotoxins from a plant-associated bacterium
Host-associated bacteria are increasingly being recognized as underexplored sources of bioactive natural products with unp...
Scalable and continuous access to pure cyclic polymers enabled by ‘quarantined’ heterogeneous catalysts
Scalable and continuous access to pure cyclic polymers enabled by ‘quarantined’ heterogeneous catalysts
Cyclic polymers are topologically interesting and envisioned as a lubricant material. However, scalable synthesis of pure ...
A modular XNAzyme cleaves long, structured RNAs under physiological conditions and enables allele-specific gene silencing
A modular XNAzyme cleaves long, structured RNAs under physiological conditions and enables allele-specific gene silencing
Nucleic-acid catalysts (ribozymes, DNA- and XNAzymes) cleave target (m)RNAs with high specificity but have shown limited e...
Publisher Correction: Standardized excitable elements for scalable engineering of far-from-equilibrium chemical networks
Authors and AffiliationsDepartment of Chemical & Biomolecular Engineering, Johns Hopkins University, Baltimore, MD, US...
Formation of a super-dense hydrogen monolayer on mesoporous silica
Formation of a super-dense hydrogen monolayer on mesoporous silica
Adsorption on various adsorbents of hydrogen and helium at temperatures close to their boiling points shows, in some cases...
The chemistry of errors
The chemistry of errors
The application of machine learning to big data, to make quantitative predictions about reaction outcomes, has been fraugh...
Producing performance-advantaged bioplastics
Producing performance-advantaged bioplastics
A grand challenge for bio-based plastics is the ability to cost-effectively manufacture high-performance polymers directly...
Pop-up rings to rule reactivity
Pop-up rings to rule reactivity
An alcohol-functionalized cyclophane has been shown to form a bowl-shaped cavity large enough to host tris(bipyridine)ruth...
Hopping protons in supramolecular catalysis
Hopping protons in supramolecular catalysis
Supramolecular catalysis can emulate many features of enzymatic transformations. Now, a complex proton wire mechanism R...
Shapeshifting xantphos
Shapeshifting xantphos
Lukas Veth and Paweł Dydio discuss the importance of ligands in transition metal catalysis, looking at the success st...
Biosynthesis and characterization of fuscimiditide, an aspartimidylated graspetide
Biosynthesis and characterization of fuscimiditide, an aspartimidylated graspetide
Microviridins and other ω-ester-linked peptides, collectively known as graspetides, are characterized by side-chain&#...
Publisher Correction: Mimicry of the proton wire mechanism of enzymes inside a supramolecular capsule enables β-selective O-glycosylations
Authors and AffiliationsDepartment of Chemistry, University of Basel, Basel, SwitzerlandTian-Ren Li, Fabian Huck & Kon...
Palladium-catalysed construction of butafulvenes
Palladium-catalysed construction of butafulvenes
Butafulvene is a constitutional isomer of benzene, comprising a cyclobutene skeleton bearing two exocyclic conjugated meth...
Filling of a water-free void explains the allosteric regulation of the β1-adrenergic receptor by cholesterol
Filling of a water-free void explains the allosteric regulation of the β1-adrenergic receptor by cholesterol
Recent high-pressure NMR results indicate that the preactive conformation of the β1-adrenergic receptor (β1AR) h...
The ribosome stabilizes partially folded intermediates of a nascent multi-domain protein
The ribosome stabilizes partially folded intermediates of a nascent multi-domain protein
Co-translational folding is crucial to ensure the production of biologically active proteins. The ribosome can alter the f...
Standardized excitable elements for scalable engineering of far-from-equilibrium chemical networks
Standardized excitable elements for scalable engineering of far-from-equilibrium chemical networks
Engineered far-from-equilibrium synthetic chemical networks that pulse or switch states in response to environmental signa...
Synthesis of a low-valent Al4+ cluster cation salt
Synthesis of a low-valent Al4+ cluster cation salt
Low-valent aluminium compounds are very reactive main-group species and have therefore been widely investigated. Since the...
Ambient-light-induced intermolecular Coulombic decay in unbound pyridine monomers
Ambient-light-induced intermolecular Coulombic decay in unbound pyridine monomers
Intermolecular Coulombic decay (ICD) is a process whereby photoexcited molecules relax by ionizing their neighbouring mole...