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Isolation and characterization of a triplet nitrene
Isolation and characterization of a triplet nitrene
Nitrene radical compounds are short-lived intermediates in a variety of nitrogen-involved transformations. They feature ei...
Catalysis-enabled amine sorting
Catalysis-enabled amine sorting
Multicomponent couplings offer powerful approaches for rapidly increasing molecular complexity, but typically require func...
Dynamic amine sorting enables multiselective construction of unsymmetrical chiral diamines
Dynamic amine sorting enables multiselective construction of unsymmetrical chiral diamines
Precisely differentiating chemicals featuring minor discrepancies is the prerequisite for achieving high selectivities in ...
Pore configuration control in hybrid azolate ultra-microporous frameworks for sieving propylene from propane
Pore configuration control in hybrid azolate ultra-microporous frameworks for sieving propylene from propane
Developing porous adsorbents for the complete sieving of propylene/propane mixtures represents an alternative method to en...
Molecular-scale dissipative chemistry drives the formation of nanoscale assemblies and their macroscale transport
Molecular-scale dissipative chemistry drives the formation of nanoscale assemblies and their macroscale transport
Fuelled chemical systems have considerable functional potential that remains largely unexplored. Here we report an approac...
Spatiotemporal protein interactome profiling through condensation-enhanced photocrosslinking
Spatiotemporal protein interactome profiling through condensation-enhanced photocrosslinking
Resolving protein–protein interactions (PPIs) inside biomolecular condensates is crucial for elucidating their funct...
Protocells by spontaneous reaction of cysteine with short-chain thioesters
Protocells by spontaneous reaction of cysteine with short-chain thioesters
All known forms of life are composed of cells, whose boundaries are defined by lipid membranes that separate and protect c...
Ubiquitin is a chemist’s playground
Ubiquitin is a chemist’s playground
Jakob Farnung and Brenda Schulman detail chemical diversification that endows the protein ubiquitin with many important ce...
Remote chirality transfer in low-dimensional hybrid metal halide semiconductors
Remote chirality transfer in low-dimensional hybrid metal halide semiconductors
In hybrid metal halide perovskites, chiroptical properties typically arise from structural symmetry breaking by incorporat...
The original caretakers of salvinorin A and recognizing Indigenous contributions to science
The original caretakers of salvinorin A and recognizing Indigenous contributions to science
Much natural-product-based drug discovery has depended on the practices of Indigenous Peoples, who have sometimes invested...
Properties governing small-molecule partitioning into biomolecular condensates
Properties governing small-molecule partitioning into biomolecular condensates
Membraneless cellular assemblies termed biomolecular condensates — into which diverse biopolymers partition — ...
Supramolecular crystals for hydrogen storage
Supramolecular crystals for hydrogen storage
Adsorbents for efficient hydrogen storage require both a high gravimetric and volumetric storage capacity. A catenation st...
The chemical sciences need introverts too
The chemical sciences need introverts too
About two thirds of western society are extroverts, but the contemplative nature of science means that this is not true of...
Author Correction: Opportunities and challenges with hyperpolarized bioresponsive probes for functional imaging using magnetic resonance
Author Correction: Opportunities and challenges with hyperpolarized bioresponsive probes for functional imaging using magnetic resonance
Authors and AffiliationsLaboratory of Molecular and Cellular Neuroimaging, International Center for Primate Brain Research...
Author Correction: Real-time monitoring of reaction stereochemistry through single-molecule observations of chirality-induced spin selectivity
Author notesThese authors contributed equally: Chen Yang, Yanwei Li.Authors and AffiliationsBeijing National Laboratory fo...
The Jekyll-and-Hyde electron transfer chemistry of hydrogen bonds
The Jekyll-and-Hyde electron transfer chemistry of hydrogen bonds
Hydrogen bonds get a bad rap in electronic materials because their weak, transient structure often results in poor perform...
Triplet metallocarbenes featuring carbon-centred spin localization
Triplet metallocarbenes featuring carbon-centred spin localization
Open-shell carbenes, which feature two unpaired electrons on a carbene carbon centre, are highly unstable compounds and ar...
Unconventional structural evolution of an oxide surface in water unveiled by in situ sum-frequency spectroscopy
Unconventional structural evolution of an oxide surface in water unveiled by in situ sum-frequency spectroscopy
Oxide–water interfaces host a wide range of important reactions in nature and modern industrial applications; howeve...
Fullerenes promote transition-metal-catalysed ammonia synthesis
Fullerenes promote transition-metal-catalysed ammonia synthesis
Although supported metal catalysts are active for ammonia synthesis, there is a need for catalysts that are active under m...
A third strand for protein–DNA interactions
A third strand for protein–DNA interactions
A method has been developed based on proximity labelling that detects the interaction of specific proteins with endogenous...
Looking into the future of hybrid glasses
Looking into the future of hybrid glasses
Glasses are typically formed by melt-quenching, that is, cooling of a liquid on a timescale fast enough to avoid ordering ...
Triazenolysis of alkenes as an aza version of ozonolysis
Triazenolysis of alkenes as an aza version of ozonolysis
Alkenes are broadly used in synthetic applications, thanks to their abundance and versatility. Ozonolysis is one of the mo...
From geranium lakes to catalysis with light
From geranium lakes to catalysis with light
Adam Noble discusses the diverse uses of eosin Y over its 150-year history, from its origin as a dye and pigment used by p...
Hydrophobic assembly of molecular catalysts at the gas–liquid–solid interface drives highly selective CO2 electromethanation
Hydrophobic assembly of molecular catalysts at the gas–liquid–solid interface drives highly selective CO2 electromethanation
Molecular catalysts offer tunable active and peripheral sites, rendering them ideal model systems to explore fundamental c...
Cobalt-catalysed desymmetrization of malononitriles via enantioselective borohydride reduction
Cobalt-catalysed desymmetrization of malononitriles via enantioselective borohydride reduction
The high nitrogen content and diverse reactivity of malononitrile are widely harnessed to access nitrogen-rich fine chemic...
Multi-stage and multi-colour liquid crystal reflections using a chiral triptycene photoswitchable dopant
Multi-stage and multi-colour liquid crystal reflections using a chiral triptycene photoswitchable dopant
The photomodulation of the helical pitch of cholesteric liquid crystals results in dynamic and coloured canvases that can ...
Abiotic anammox by a naturally occurring mineral
Abiotic anammox by a naturally occurring mineral
The enzymatic conversion of NH4+ and NO2– to N2 catalysed by bacteria is critical to maintain nitrogen balance in th...
Charting the ligandable proteome for stereoselective interactions
Charting the ligandable proteome for stereoselective interactions
Determining the ligandability of the human proteome can provide key insights to characterize biological processes and prom...
Biocatalytic asymmetric aldol addition into unactivated ketones
Biocatalytic asymmetric aldol addition into unactivated ketones
Enzymes are renowned for their catalytic efficiency and selectivity, but many classical transformations in organic synthes...
Integrated photochemical strategy for alkene synthesis from diverse substrates
Integrated photochemical strategy for alkene synthesis from diverse substrates
Despite advances, a general olefination strategy for the direct conversion of carboxylic acids, alcohols and alkanes into ...
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