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Light-promoted aromatic denitrative chlorination
Light-promoted aromatic denitrative chlorination
Nitroarenes are readily accessible bulk chemicals and can serve as versatile starting materials for a series of synthetic ...
Synthesis of pillar-layered metal–organic frameworks with variable backbones through sequence control
Synthesis of pillar-layered metal–organic frameworks with variable backbones through sequence control
The properties and functions of metal–organic frameworks (MOFs) can be tailored by tuning their structure, including...
An open-shell Ir(II)/Ir(IV) redox couple outperforms an Ir(I)/Ir(III) pair in olefin isomerization
An open-shell Ir(II)/Ir(IV) redox couple outperforms an Ir(I)/Ir(III) pair in olefin isomerization
Open-shell systems based on first-row transition metals and their involvement in various catalytic processes are well expl...
Isolation of a planar π-aromatic Bi5− ring in a cobalt-based inverse-sandwich-type complex
Isolation of a planar π-aromatic Bi5− ring in a cobalt-based inverse-sandwich-type complex
Monocyclic π-aromatic compounds are ubiquitous throughout almost all fields of natural sciences—as synthons in ...
Author Correction: Cytoskeleton-functionalized synthetic cells with life-like mechanical features and regulated membrane dynamicity
Open Access This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 ...
Publisher Correction: Protocells by spontaneous reaction of cysteine with short-chain thioesters
Publisher Correction: Protocells by spontaneous reaction of cysteine with short-chain thioesters
Author notesYei-Chen LaiPresent address: Department of Chemistry, National Chung Hsing University, Taichung City, TaiwanTh...
Author Correction: Discovery of the selenium-containing antioxidant ovoselenol derived from convergent evolution
Author notesThese authors contributed equally: Chase M. Kayrouz, Kendra A. Ireland.Authors and AffiliationsDepartment of C...
Vibrational weak and strong coupling modify a chemical reaction via cavity-mediated radiative energy transfer
Vibrational weak and strong coupling modify a chemical reaction via cavity-mediated radiative energy transfer
Controlling reaction outcomes through external influences is a central goal in chemistry. Vibrational coupling between mol...
The mechanism of amyloid fibril growth from Φ-value analysis
The mechanism of amyloid fibril growth from Φ-value analysis
Amyloid fibrils are highly stable misfolded protein assemblies that play an important role in several neurodegenerative an...
Engineering a DNA polymerase for modifying large RNA at specific positions
Engineering a DNA polymerase for modifying large RNA at specific positions
The synthesis of large RNA with precise modifications at specific positions is in high demand for both basic research and ...
Coacervate vesicles assembled by liquid–liquid phase separation improve delivery of biopharmaceuticals
Coacervate vesicles assembled by liquid–liquid phase separation improve delivery of biopharmaceuticals
Vesicles play critical roles in cellular materials storage and signal transportation, even in the formation of organelles ...
Defining proteoform-specific interactions for drug targeting in a native cell signalling environment
Defining proteoform-specific interactions for drug targeting in a native cell signalling environment
Understanding the dynamics of membrane protein–ligand interactions within a native lipid bilayer is a major goal for...
Mimicking of differentiation in pluripotent synthetic cells
Mimicking of differentiation in pluripotent synthetic cells
An essential feature of pluripotent synthetic cells is that they must become desensitized to certain differentiation signa...
Accelerating stereoselective radical cross-couplings
Accelerating stereoselective radical cross-couplings
Aminoalcohols are vital motifs in chemical synthesis; however, traditional synthetic technologies relying on polar disconn...
Bottleable triplet nitrenes
Bottleable triplet nitrenes
Nitrenes are compounds featuring a monovalent nitrogen atom, and they are typically formed as transient intermediates in o...
Practical electronics and robotics for chemists
To the Editor — McCluskey and colleagues recently emphasized the importance of computers and coding in chemical education1...
Remote control of chirality in hybrid perovskite materials
Remote control of chirality in hybrid perovskite materials
Chirality in hybrid perovskite semiconductors can advance their application in modern electronics, but their production &#...
Porphyrins are nature’s workhorse
Porphyrins are nature’s workhorse
Paulina Krzyszowska and Ewa Pacholska-Dudziak recap the history of porphyrins, their biological relevance, and discuss exa...
Self-assembly of chiroptical ionic co-crystals from silver nanoclusters and organic macrocycles
Self-assembly of chiroptical ionic co-crystals from silver nanoclusters and organic macrocycles
Atomically precise nanoclusters can be assembled into ordered superlattices with unique electronic, magnetic, optical and ...
A pseudo-cubic metal–organic cage with conformationally switchable faces for dynamically adaptive guest encapsulation
A pseudo-cubic metal–organic cage with conformationally switchable faces for dynamically adaptive guest encapsulation
The creation of hosts capable of accommodating different guest molecules may enable these hosts to play useful roles in ch...
Synthesis of three-dimensional covalent organic frameworks through a symmetry reduction strategy
Synthesis of three-dimensional covalent organic frameworks through a symmetry reduction strategy
Three-dimensional (3D) covalent organic frameworks (COFs) hold significant promise for a variety of applications. However,...
A trimetallic bismuth(I)-based allyl cation
A trimetallic bismuth(I)-based allyl cation
The chemistry of low-valent bismuth compounds has recently unlocked new concepts in catalysis and unique electronic struct...
Intellectual frameworks to understand complex biochemical systems at the origin of life
Intellectual frameworks to understand complex biochemical systems at the origin of life
Understanding the emergence of complex biochemical systems, such as protein translation, is a great challenge. Although sy...
Uniform single-crystal mesoporous metal–organic frameworks
Uniform single-crystal mesoporous metal–organic frameworks
The synthesis of mesoporous metal–organic frameworks (meso-MOFs) is desirable as these materials can be used in vari...
Stereoselective amino alcohol synthesis via chemoselective electrocatalytic radical cross-couplings
Stereoselective amino alcohol synthesis via chemoselective electrocatalytic radical cross-couplings
Amino alcohols are vital in natural products, pharmaceuticals and agrochemicals, and as key building blocks for various ap...
Synthesis of tertiary alkyl amines via photoinduced copper-catalysed nucleophilic substitution
Synthesis of tertiary alkyl amines via photoinduced copper-catalysed nucleophilic substitution
In view of the high propensity of tertiary alkyl amines to be bioactive, the development of new methods for their synthesi...
Cytoskeleton-functionalized synthetic cells with life-like mechanical features and regulated membrane dynamicity
Cytoskeleton-functionalized synthetic cells with life-like mechanical features and regulated membrane dynamicity
The cytoskeleton is a crucial determinant of mammalian cell structure and function, providing mechanical resilience, suppo...
Four-electron reduction of benzene by a samarium(ii)-alkyl without the addition of external reducing agents
Four-electron reduction of benzene by a samarium(ii)-alkyl without the addition of external reducing agents
Benzene reduction by molecular complexes remains an important synthetic challenge, requiring harsh reaction conditions inv...
In situ nonlinear optical spectroscopy for probing buried oxide–water interfaces
In situ nonlinear optical spectroscopy for probing buried oxide–water interfaces
Oxide–water interfaces are ubiquitous in nature and technological processes, but their characterization is difficult...
Adaptive metal ion transport and metalloregulation-driven differentiation in pluripotent synthetic cells
Adaptive metal ion transport and metalloregulation-driven differentiation in pluripotent synthetic cells
Pluripotent cells can yield different cell types determined by the specific sequence of differentiation signals that they ...
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