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MOF (UiO-66-NH2)@COF (TFP-TABQ) Hybrids via On-surface Condensation Reactions for Sustainable Energy Storage
Core-shell MOF@COF hybrids were synthesized via subsequent modification of MOF UiO-66-NH2 with 1,3,5-triformylphloroglucin...
Rh(III)-Catalyzed Selective C2 C-H Acyloxylation of Indoles
We, herein, present the first highly regio- and chemoselective C2 C-H acyloxylation of indole under rhodium catalysis and ...
Ammonia Synthesis by the Reductive N-N Bond Cleavage of Hydrazine Using an Air-Stable, Phosphine-Free Ruthenium Catalyst
An effective molecular catalyst to reduce hydrazine efficiently to ammonia using a suitable reductant and proton source is...
Chronological Development of Functional Fluorophores for Bio-Imaging
Functional fluorophores represent an emerging research field, distinguished by their diverse applications, especially in s...
Mixed-magnesium/zinc calix[4]arene complexes: Structure, and ring opening polymerisation studies
Different combinations of organomagnesium reagents and zinc bromide react with either 1,3-dimethoxy-4-tert-butylcalix[4]ar...
Isolated Ni atoms catalyst supported on Ti3C2Tx with asymmetrical C-Ni-N structure for hydrogen evolution reaction
Single-atom catalysts (SACs), distinguished by their exceptional atomic efficiency and modifiable coordination structures,...
Highly luminescent olefin-linked covalent organic frameworks
A new olefin-linked covalent organic framework (COF) was developed using 1,3,5-triformylbenzene (TFB) and tetraethyl p-xyl...
Injectable Cell-Laden Silk Acid Hydrogel
This study presents an injectable cell-laden hydrogel system based on silk acid, a carboxylated derivative of natural silk...
Engineering defect-rich Prussian blue analogs composite for enhanced Cs+ removal performance
Using novel irregular honeycombed N-doped porous carbon (NPC) as both support and defect inducer, the defect-rich Zn-PBA w...
Core-shell oxygen-deficient Fe2O3 polyhedron serves as an efficient host for sulfur cathode
Herein, rich oxygen-defects core-shell Fe2O3–x@C polyhedral sulfur host was prepared, which effectively promoted the elect...
Continuous selective conversion of methane to methanol over Cu-KFI zeolite catalyst using water-O2 mixture as the oxygen source
Continuous catalytic oxidation of methane to methanol is reported on Cu-KFI zeolite using water-O2 mixture as the oxidant....
Efficient Post-synthesis Incorporation and Conjugation of Reactive Ketones in RNA via 2’-Acylation
Despite the broad utility of ketones in bioconjugation, few methods exist to introduce them into RNA. Here we develop high...
Molybdenum Sulphide Clusters as Redox Active Supports for Low-Valent Uranium
The preparation of an actinide substituted cubane cluster, (Cp*3Mo3S4)Cp*UI2, and its reduced derivatives are reported. St...
Engineered fluorogenic HaloTag ligands for turn-on labelling in live cells
Recent years have seen dramatic improvements in the design of organic fluorophores based on limiting non-radiative decay p...
Efficient End-Group Functionalization and Diblock Copolymer Synthesis via Au(III) Polymer Reagents
Herein, we describe the synthesis of bench-stable organometallic Au(III) terminated polymer reagents. These reagents media...
Fabrication of Multi-functional Molecular Tunnelling Junctions by Click Chemistry
The continuous advance in molecular electronics demands increasing functionality and diversity of integrated molecular jun...
Dopamine oxidation promoted by human telomeric DNA models in the presence of a Cu(II) terpyridine chelate
We found that under oxidative stress condition the coexistence of human telomeric DNA (HT-DNA) and copper-terpyridine meta...
Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations of Carbamimidates
Transition metal-catalyzed asymmetric nitrene transfer is a powerful method for the generation of enantioenriched amines f...
PbTeB4O9: A Lead Tellurium Borate with Unprecedented Fundamental Building Block [B4O10] and Large Birefringence
Herein, the first lead tellurium borate, PbTeB4O9 with unprecedented fundamental building block [B4O10] was successfully s...
Programmable photochemical deoxygenation for 2.5D grayscale printing
Homomolecular photon upconversion-induced radical polymerization in an aerated DMSO solution occurs where molecular oxygen...
Highly photoactive Ir(III)–Pt(IV) heterometallic conjugates for anticancer therapy
For the first time, this study reported the photoactivatable activity of Ir(III)-Pt(IV) heterometallic conjugates, which w...
Rh(III)-catalyzed oxidative [4+2] annulation of 2-arylquinoxalines and 2-aryl-2H-indazoles with allyl alcohols
Synthesis of functionalized benzo[a]phenazines and indazolo[2,3-a]quinolines have been developed through a Rh(III)-catalyz...
Synthesis of Oxime Ethers via A Formal Reductive O–H Bond Insertion Reaction of Oximes to α-Keto Esters
This study describes an efficient approach to access oxime ethers via P(III)-mediated O–H bond insertion reaction of oxime...
Organic electrodes based on redox-active covalent organic frameworks for lithium batteries
Electroactive organic materials have received much attention as alternative electrodes for metal-ion batteries due to thei...
Organophotocatalytic α-deuteration of unprotected primary amines via H/D exchange with D2O
We report a straightforward H/D exchange method for the synthesis of α-deuterated primary amines from a diverse set of pri...
Reductive Cyclodimerization of Chalcones: Exploring the “Self-adaptability” of Galvanostatic Electrosynthesis
The “self-adaptability” of galvanostatic electrolysis is shown to assist a multistage unprecedented chemo- and diastereose...
Electronic structure engineering on Co-based metal-organic frameworks for concurrent electrocatalytic hydrogen generation and formate electrosynthesis
A facile one-step solvothermal method was developed to synthesize Ir-doped Co-based metal-organic framework (CoIr-MOF) nan...
High Valence Binary Metal-Organic Framework as Electrode Material for Aqueous Asymmetric Supercapacitor
This study presents the chemical transformation of nickel-based metal-organic frameworks into binary metal-organic framewo...
Noncovalent Backbone Planarization Strategy Increase NIR-II Extinction Coefficients for Gas/Phototheranostic Applications
We propose a noncovalent backbone planarization strategy to fabricate a gas/phototheranostic nanocomposite (B-E-NO NPs) in...
Cr-catalysed ethylene dimerization in an ionic liquid-organic solvent biphasic system with perfect 1-butene selectivity
Cr-catalyzed ionic liquid-organic biphasic ethylene dimerization was realized with 100% 1-butene selectivity. The perfect ...
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