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Gold-catalyzed benzannulations of 2-alkenylindoles with alkynes: a protecting-group-free regioselective approach to carbazoles
A gold(I)-catalyzed protecting-group-free benzannulation approach to functionalized NH-carbazoles was accomplished via the...
Green synthesis for diverse bioactive benzo-fused spiroindolines through DBU-catalysed post-Ugi double cyclization
A metal-free protocol utilizing DBU catalysis for post-Ugi amide-ester exchange and Conia-ene double cyclization has succe...
Rhodium-catalyzed three-component C(sp3)/C(sp2)−H activation enabled by two-fold directing groups strategy.
The Rh-catalzyed three-component C(sp3)/C(sp2)−H activation has been achieved through a two-directing group strategy. This...
Correction: A closer look at ligand specificity for cellular activation of NOD2 with synthetic muramyl dipeptide analogues
Correction for ‘A closer look at ligand specificity for cellular activation of NOD2 with synthetic muramyl dipeptide analo...
Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters
Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters, [Nb6O19@Ag45(iPrS)23(CH3COO)14] (Ag45) and ...
Metal- and solvent-free domino reaction of 2-isocyanophenol esters to benzoxazines: long-range 1,5-acyl migration on 1,4-diazabutatriene
The first example of intramolecular nucleophilic addition of 1,4-diazabutatriene to ester is disclosed. This approach prov...
Iron-catalyzed Aerobic Oxidation of Silyl Ethers to Carboxylic Acids
A direct aerobic oxidation of silyl ethers to carboxylic acids has been developed. The mild reaction conditions lead to a ...
Mechanistic Variances in NO Release: Ortho vs. Meta Isomers of Nitrophenol and Nitroaniline
The NO release following 266 nm photolysis of ortho and meta isomers of nitrophenol and nitroaniline shows bimodal transla...
Iridium(III)-catalyzed photoredox cross-coupling of alkyl bromide with trialkyl amines: Access to α-alkylated aldehydes
A C(sp3)-C(sp3) cross coupling approach based on an Iridium-photocatalytic radical process has been developed enabling the...
Recent Progresses and Perspectives on Metal-organic Frameworks as Solid-state Electrolytes for Lithium Batteries
Solid-state electrolytes (SSEs) are the key materials in the new generation of all-solid-state lithium ion/metal batteries...
Effect of Incorporation of Gallium Ion into Silver Indium Sulfide Nanocrystals
Various methods thoroughly investigate the gallium ion incorporation mechanism into silver indium gallium sulfide (AIGS) n...
Fluorescent Coumarin-Alkynes for Labeling of Amino Acids and Peptides via Manganese(I)-Catalyzed C–H Alkenylation
The late-stage fluorescent labeling of structurally complex peptides bears immense potential for molecular imaging. Herein...
Cold denaturation of DNA origami nanostructures
The coupling of structural transitions to heat capacity changes leads to destabilization of macromolecules at both, elevat...
Luminescence center modulation towards a narrow-band green phosphor: mechanism and backlighting display application
A highly efficient and stable green phosphor with narrow-emission band was achieved in a hexagonal aluminate based on the ...
Photoredox-catalyzed alkylarylation of activated alkenes via a ring open/Truce-Smiles rearrangement cascade
A photoredox-catalyzed alkylarylation of activated alkenes via a radical C-C bond cleavage/Truce-Smiles rearrangement casc...
Harnessing Solid-State Ion Exchange for the Environmentally Benign Synthesis of High-Efficiency Mn4+-Doped Phosphors
In this study, a solid-state ion exchange (SSIE) method is proposed to synthesize a series of Mn4+-doped fluoride phosphor...
Biphasic Water-Oil Systems for Functional Augmentation of Probiotic Lactobacillus acidophilus Nanoencapsulated in Luteolin-Fe3+ Shells
Single-cell nanoencapsulation (SCNE) has great potential in the enhancement of therapeutic effects of probiotic microbes. ...
Gram‐scale synthesis small-sized PtM intermetallics as high-performance catalysts for the hydrogen evolution reaction
Pt-based intermetallics exhibit excellent activity in electrocatalysis. However, their controlled syntheses remain difficu...
Bulk ferromagnetism in cleavable van der Waals telluride NbFeTe2
A van der Waals telluride, NbFeTe2, has been synthesized using chemical vapor transport reactions. The optimized synthetic...
Prussian Blue Analogue Derived from Leather Waste as Bifunctional Catalyst in Zinc-Air Batteries
Prussian blue analogue was synthesized by using biomass leather waste as precursor doping with Co2+ ion. This material, se...
Nitrogen-Doped Carbon Nanosheet Composited Platinum-Cobalt Single Atom Alloy Catalyst for Effective Hydrogen Evolution Reaction
An electrocatalyst with ultra-small PtCo single atom alloy species evenly dispersed on nitrogen-doped ultra-thin carbon na...
Fluorescence monitoring of refluxed tyrosinase by endoplasmic reticulum-localized enzymatic activity-based sensing
A tyrosinase-activatable fluorescence probe with endoplasmic reticulum targetability was proposed for the first time. It c...
Electron-insulating Li2O protection layer endowing Li-Cu-Zn ternary alloy composite anode with high performance
We report a electron-insulating layer of Li2O nanoparticles passivated Li-rich Li-Cu-Zn ternary alloy as advanced Li anode...
Organic Hole Transport Materials for High Performance PbS Quantum Dot Solar Cells
We developed a triazatruxene-based hole transport material (HTM), 3Ka-DBT-3Ka, aiming to enhance band alignment and augmen...
Tuning the redox profile of the 6,6’-biazulenic platform through functionalization along its molecular axis
The E1/2 potential associated with reduction of the linearly-functionalized 6,6’-biazulenic scaffold is accurately correla...
Enabling wide temperature battery operation with hybrid lithium electrolytes
We demonstrate that an ionic liquid 1-ethyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide combined with propylen...
Recent advances in electrosynthesis of H2O2 via two-electron oxygen reduction reaction
The electrosynthesis of hydrogen peroxide (H2O2) via a selective two-electron oxygen reduction reaction (2e- ORR) presents...
Chemical Control of CRISPR/Cpf1 Editing via Orthogonal Activation and Deactivation of Crosslinked crRNA
Through the integration of CRISPR/Cpf1 with optogenetics and a reduction-responsive motif, we have developed a photoactiva...