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Synthesis and photoluminescence properties of polymer chains based on pre-designed heterometallic Al4Ln4 molecular rings
Present herein is a series of chain compounds based on pre-designed heterometallic aluminum-lanthanide (Al-Ln) Al4Ln4 mole...
Catalysts development for O2-assisted oxidative dehydrogenation of propane to propylene
O2-assisted oxidative dehydrogenation of propane (O2-ODHP) technology could convert abundant shale gas into propylene as a...
Alkyl Nitrite-Enabled Palladium-Catalyzed Terminal Selective Oxidative Cyclization of 4-Penten-1-ols
Oxidative cyclization of 4-penten-1-ols using a Pd catalyst and n-BuONO or n-BuONO/p-benzoquinone afforded 3-hydroxy- and ...
Molecular Engineering of Metal-based Photosensitizers with Narrow Band Gap for Efficient Photodynamic Therapy
Three iridium(III) complexes were designed with the purpose to elucidate the photo-physicochemical properties of iridium(I...
Iridium-catalyzed diacylmethylation of tyrosines and its peptides with sulfoxonium ylides
Pyridyloxy-directed Ir(III)-catalyzed diacylmethylation of protected tyrosines was achieved with alkyl and (hetero)aryl su...
A lateral flow assay strip for simultaneous detection of miRNA and exosome in liver cancer
By employing aptamer as the bridge and combining catalytic hairpin assembly with the Au aggregation amplification effect, ...
Aptamer-assisted Phage Display: Enhancing Checkpoint Inhibition with a Peptide and an Aptamer Targeting Distinct Sites on a Single PD-L1 Protein
Utilizing a novel approach known as Aptamer-assisted Phage Display (APD), we identified an anti-PD-L1 peptide, NV Pep, cap...
Visualizing nanoscale heterogeneity in perylene thin films via tip-enhanced photoluminescence with unsupervised machine learning
We investigate the properties of ultrathin 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) films using a combination of t...
Fluorescence-enhanced supra-amphiphilies based on pillar[5]arene: construction, controllable self-assembly and application in cell-imaging
Fluorescence-enhanced supra-amphiphilies based on (WP5)2⊃ENDTn were constructed successfully. When n = 9, it can self-asse...
Hybrid homogeneous/heterogeneous relay catalysis for efficient synthesis of 5-aminomethyl-2-furancarboxylic acid from HMF
Here we present a hybrid catalytic pathway for efficient synthesis of 5-aminomethyl-2-furancarboxylic acid (AMFC), a bio-b...
Hydroazidation of trifluoromethyl alkenes with trimethylsilyl azide enabled by organic photoredox catalysis
Herein, we report an organic photoredox catalyzed hydroazidation of trifluoromethyl alkenes with user-friendly trimethylsi...
Multiscale characterizations of structural evolution in mesoporous CeO2
Through in situ ultra-small-angle and wide-angle x-ray scattering, we simultaneously track the structural parameters of me...
Above Room Temperature Ferroelectric Two-Dimensional Halide Double Perovskite with Direction Dependent Properties
Herein, we introduce a new non-centrosymmetric 2D halide double perovskite Cl0.26Br3.74PA4AgSbBr8 (CPAS) with A-site linke...
Advances and Challenges in Molecular Engineering of 2D/3D Perovskite Heterostructures
Organic-inorganic hybrid perovskite have been intensively studied in the past decades due to their outstanding performance...
A review on oxime functionality: An ordinary functional group with significant impacts in Supramolecular Chemistry
The oxime functional group is pivotal in chemistry, finding extensive applications in medical science, catalysis, organic ...
Mixing and Matching N,N- and N,O-Chelates in Anionic Mg(I) Compounds: Synthesis and Reactivity with RN=C=NR and CO
Reduction of [Mg(NON)]2 ([NON]2– = [O(SiMe2NDipp)2]2–, Dipp = 2,6-iPr2C6H3) affords Mg(I) species containing NON- and NNO-...
Asymmetric dearomatization of benzyl 1-naphthyl ethers via [1,3] O-to-C rearrangement
A catalytic asymmetric dearomatization reaction of benzyl 1-naphthyl ethers accelerated by a chiral N,Nʹ-dioxide/Co(II) co...
Spin polarization strategy regulates heterogeneous catalytic activity performance: from fundamental to application
In recent years, there has been significant attention towards the development of catalysts that exhibit superior performan...
2D Metal-Organic Frameworks Bearing Butterfly-shaped Metal-bis(dithiolene) Linkers from Dithiol-functionalized Benzenedicarboxylic Acid
Assembly between 1,4-dicarboxylbenzene-2,3-dithiol (H2dcbdt) and transition metal ions successfully produced 2D metal-orga...
Electro-catalytic water-to-oxygenates conversion: redox-mediated versus direct oxygen transfer
Electro-catalytic oxygenation of hydrocarbons with high selectivity has attracted much attention for its advantages of sus...
3D hierarchical Ti3C2/TiO2 composite via in situ oxidation for improved lithium-ion storage
To address the intrinsic limitations of both TiO2 and MXenes, we propose an effective strategy for the engineering of a 3D...
Oxidation mechanism of phenols by copper(II)-halide complexes
Oxidation mechanism of phenols by tetrahedral copper(II)-halide complexes was investigated to demonstrate that phenols hav...
Self-reporting Intracellular Delivery Agent for Singlet Oxygen
1,4-dimethylphenazine endoperoxide releases singlet oxygen with a half-life of 89 hours at 37 oC. The thermal cycloreversi...
Halogen Bonding Aza-BODIPYs for Anion Sensing and Anion Binding-Modulated Singlet Oxygen Generation
Two novel aza-BODIPY based anion sensors, decorated with halogen bonding recognition sites, are capable of detecting halid...
Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs
This article is Open Access...
Amplification of Negative Gas Adsorption in a multivariate framework
The approach of multivariate MOFs was used to fine-tune the mechanical properties of the flexible framework DUT-49. In sit...
Sensitive subcellular scale and real-time detection of hydrogen peroxide by W-doped Pt microelectrode
Real-time detection of hydrogen peroxide (H2O2) in a subcellular scale is of importance for clinical diagnosis and physiop...
Visible-light-induced Ritter-type amidation of α-hydroxy ketones in the selectively synthesis of α,α-diamido and monoamido ketones
A visible light induced, transition metal-free oxidative dehydroxylation and C-H amidation of α-hydroxy ketones involving ...
Intermediates involved in the Reduction of SO2: Insight into the mechanism of Sulfite Reductases
Sulfite Reductase (SiR) catalyze the reduction of SO32- to H2S in both biosynthetic sulfur assimilation and dissimilation ...
Palladium-Catalyzed Site-Selective Functionalization of Unactivated Alkenes with Vinylcyclopropanes Aided by Weakly Coordinating Native Amides
Herein, we have demonstrated a palladium-catalyzed regioselective allylation of unactivated alkenes with vinylcyclopropane...
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