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Metathesis chemistry of inorganic cumulenes driven by B–O bond formation
The reaction chemistry of an unprecedented ‘inorganic cumulene’ - featuring a five-atom BNBNB chain - towards C=O (and rel...
Unveiling the Enzymatic Pathway of UMG-SP2 Urethanase: Insights into Polyurethane Degradation at the Atomic Level
The recently discovered metagenomic urethanases UMG-SP1, UMG-SP2, and UMG-SP3 have emerged as promising tools to establish...
Correction: Enhanced catalytic activity of solubilised species obtained by counter-cation exchange of K{CoII1.5[FeII(CN)6]} for water oxidation
Correction for ‘Enhanced catalytic activity of solubilised species obtained by counter-cation exchange of K for water oxid...
Long oligos: direct chemical synthesis of genes with up to 1,728 nucleotides
The longest oligos that can be chemically synthesized are considered to be 200-mers. Here, we report direct synthesis of a...
A Perspective on Field-effect in Energy and Environmental Catalysis
The development of catalytic technologies for sustainable energy conversion is a critical step toward addressing fossil fu...
Advanced Fabrication Techniques for Polymer-Metal Nanocomposite Films: State-of-the-Art Innovations in Energy and Electronic Applications
Polymer-metal nanocomposites are a fascinating class of materials that synergize the distinct properties of polymers and m...
Enhancing Electrocatalytic Hydrogen Evolution via Engineering Unsaturated Electronic Structures in MoS₂
The search for efficient, earth-abundant electrocatalysts for the hydrogen evolution reaction (HER) has identified unsatur...
Aromatic-Aromatic Interactions Drive Fold Switch of GA95 and GB95 with Three Residue Difference
Proteins typically adopt a single fold to carry out their function, but metamorphic proteins, with multiple folding states...
Correction: FragGen: towards 3D geometry reliable fragment-based molecular generation
Correction for ‘FragGen: towards 3D geometry reliable fragment-based molecular generation’ by Odin Zhang et al., Chem. Sci...
The inductive effect does not explain electron density in haloacetates: Are our textbooks wrong?
The inductive effect is a central concept in chemistry and is often exemplified by the pKa values of acetic acid derivativ...
Intrinsically Chiral Thermoresponsive Assemblies from Achiral Clusters: Enhanced Luminescence and Optical Activity through Tailor-made Chiral Additives
Chiral metal clusters, due to their intriguing optical properties and unique resemblance in size with biomolecules, have g...
pH-Responsive Nanotubes from Asymmetric Cyclic Peptide-Polymer Conjugates
Self-assembling cyclic peptide nanotubes are fascinating supramolecular systems with promising potential for various appli...
Metal-organic frameworks generated from oligomeric ligands with functionalized tethers
Metal-organic frameworks (MOFs) can be prepared from oligomeric organic ligands to prepare materials referred to as oligoM...
Rare Earth Benzene Tetraanion-Bridged Amidinate Complexes
The benzene tetraanion-bridged rare earth inverse arene amidinate complexes [2(μ-η6:η6-C6H6)] (2-Ln, Ln = Gd, Tb, Dy, Y; P...
Buried Interface Management toward High-Performance Perovskite Solar Cells
The interface between the perovskite layer and the electron transport layer is an extremely important factor that cannot b...
Interplay between A-site and oxygen-vacancy ordering, and mixed electron/oxide-ion conductivity in n = 1 Ruddlesden−Popper perovskite Sr2Nd2Zn2O7
Oxygen vacancies in Ruddlesden−Popper (RP) perovskites (PV) [AO][ABO3]n play a pivotal role in engineering functional prop...
570 nm-/770 nm Light-Excited Deep-Red Fluorescence Switch Based on Dithienylethene Derived from BF2-Curcuminoid
Developing dithienylethene (DTE)-based fluorescence switches triggered by biocompatible visible light has always been a lo...
Rational Design of a Series of Non-centrosymmetric Antiperovskite and double Antiperovskite Borate Fluorides
Non-centrosymmetric (NCS) compounds can exhibit many symmetry-dependent functional properties yet their rational structure...
Kinetics and Dynamics of Atomic-Layer Dissolution on Low-Defect Ag
Electrochemical metal dissolution reaction is a fundamental process in various critical technologies, including metal anod...
Folded-Twisted Mechanisms Control Dynamic Redox Properties, Photophysics and Electron Transfer of Anthanthrene-Quinodimethanes
The synthesis, electrochemical, spectroelectrochemical, photophysical and light induced electron transfer reactions in two...
Probing the Synergistic Effects of Amino Compounds in Mitigating Oxidation in 2D Ti3C2Tx MXene nanosheets in Aqueous Environment
The shelf life of 2D MXenes in functional devices and colloidal dispersions is compromised due to oxidation in the aqueous...
pH-Responsive Supramolecular Switch of Rationally Designed Dipyrroethene-Based Chromophore
Herein, we present a strategy to access a novel class of pH-responsive, dual-state emissive (DSE), highly fluorescent pyrr...
Asymmetric Rh-O-Co bridge sites enable superior bifunctional catalysis for hydrazine-assisted hydrogen production
Hydrazine-assisted water splitting is a promising strategy for energy-efficient hydrogen production, yet challenges remain...
Diacetylene-bridged covalent organic framework as crystalline graphdiyne analogue for photocatalytic hydrogen evolution
Graphdiyne (GDY) alone as photocatalyst is unsatisfactory because of low crystallinity, limited regulation of band gap, we...
Controllable Reconstruction of Lignified Biomass with Molecular Scissors to form Carbon Framework for Highly Stable Li Metal Battery
Lithium metal batteries (LMBs) promise high-energy-density storage but face safety issues due to dendrite-induced lithium ...
Two-photon brightness of NIR-emitting, atomically precise DNA-stabilized silver nanoclusters
Near-infrared (NIR) emitters with high two-photon absorption (2PA) cross-sections are of interest to enable in vivo imagin...
Synthesis of fluorine-containing bicyclo[4.1.1]octenes via photocatalyzed defluorinative (4+3) annulation of bicyclo[1.1.0]butanes with gem-difluoroalkenes
Although bicyclo[4.1.1] systems are privileged scaffolds in many natural products and drug molecules, efficient synthetic ...
Phosphite Mediated Molecular Editing via Switch to meta-C−H Alkylation of Isoquinolines:  Emergence of a Distinct Photochemical [1,3] N to C Rearrangement
Isoquinoline core is present in one of the largest subsets of bioactive natural products. The multifunctional isoquinoline...
Bismuth oxide−modified copper host achieving bubble−free and stable potassium metal batteries
Due to the minimal electrochemical oxidation-reduction potential, the potassium (K) metal anode has emerged as a focal in ...
Determinants of regioselectivity of heterostructures in cation exchange reactions
Cation exchange (CE) reaction offers a remarkable opportunity to create versatile metal sulfide nanocrystals (NCs) with ar...
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