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Deciphering the chemical bond of trivalent oxygen atom in oxygen doped graphene
Recently planar and neutral tricoordinated oxygen embedded in graphene was imaged experimentally (Nat. Commun. 10, 4570−45...
Influence of the substitution position on spin communication in photoexcited perylene−nitroxide dyads
By virtue of the modularity of their structures, their tunable optical and magnetic properties, and versatile applications...
Thermoswitchable Catalysis to Inhibit and Promote Plastic Flow in Vitrimers
Acid-base catalysis is a common strategy to induce covalent bond exchanges in dynamic polymer networks. Strong acids or st...
Lanthanide MOF-Based Luminescent Sensor Arrays for the Detection of Castration-Resistant Prostate Cancer Curing Drugs and Biomarkers
In recent years, castration-resistant prostate cancer (CRPC) has profoundly impacted the lives of many men, and early diag...
Visible-Light-Enabled Stereoselective Synthesis of Functionalized Cyclohexylamine Derivatives via [4 + 2] Cycloadditions
An unprecedented intermolecular [4 + 2] cycloaddition of benzocyclobutylamines with α-substituted vinylketones enabled by ...
All-Visible-Light-Driven Stiff-stilbene Photoswitches
Molecular photoswitches are potent tools to construct dynamic functional systems and responsive materials in that can be c...
Rh(III)-Catalyzed sp3/sp2–C-H Heteroarylations via Cascade C-H Activation and Cyclization
The development of an efficient strategy for facile access to quinoline-based bis-heterocycles holds paramount importance ...
Designed Enhancement in Hydroxide Ion Conductivity of Viologen-Bakelite Organic Frameworks for Flexible Rechargeable Zinc-Air Battery
Quasi-solid-state rechargeable zinc-air batteries (ZABs) are suitable for portable clean energy due to their high energy a...
Enantioselective organocatalytic strategies to noncanonical α-amino acids
Organocatalytic asymmetric synthesis has evolved over the years and continues to attract the interest of many researchers ...
Photoswitching the Fluorescence of Nanoparticles for Advanced Optical Applications
The dynamic optical response property and the distinct features of nanomaterials make photoswitchable fluorescent nanopart...
Singlet-Fission in TIPS-Anthracene Thin Films
Singlet fission is an exciton multiplication process that allows for the conversion of one singlet exciton into two triple...
Selective Adsorption of Fluorinated Super Greenhouse Gases within a Metal–Organic Framework with Dynamic Corrugated Ultramicropores
Perfluorocompound (PFC) gases play vital roles in microelectronics processing. Requirements for ulta-high purities traditi...
The circularly permuted globin domain of Androglobin exhibits atypical heme stabilization and nitric oxide interaction
In the decade since the discovery of androglobin, a multi-domain hemoglobin of metazoans associated with ciliogenesis and ...
Visible-light-driven alkene dicarboxylation with formate and CO2 under mild conditions
The low-cost formate salt was used as the reductant and part of the carboxyl source in a visible-light-driven dicarboxylat...
Fluorescent carbazole-derived α-amino acids; structural mimics of tryptophan
Fluorescent tags are commonly used for imaging of proteins and peptides during biological events; however, the large size ...
Ultrafast Symmetry-Breaking Charge Separation in PMI-embedded Multichromophores: Impact of Regioisomerism
Symmetry-breaking charge separation (SB-CS) has recently evolved as an emerging concept offering its potential in the late...
Unravelling the Role of Spin-Vibrational Coupling in Designing High-Performance Pentagonal Bipyramidal Dy(III) Single Ion Magnets
At the cutting edge of high-performance single-molecule magnets (SMMs) lie lanthanide-based complexes, renowned for their ...
Hard Carbon for Sodium-ion Batteries: Progress, Strategy and Future Perspective
Because of abundant resource, low cost and high reversible specific capacity, hard carbon (HC) is considered to be the mos...
Vibrational Spectroscopy and Dissociation Dynamics of Cyclohexyl Hydroperoxide
Organic hydroperoxide (ROOH) are ubiquitous in the atmospheric oxidation of volatile organic compounds (VOCs) as well as i...
Opportunities and Challenges for Plastic Depolymerization by Biomimetic Catalysis
Plastic waste has imposed significant burdens on the environment. Chemical recycling allows for repeated regeneration of p...
Intramolecular chaperone-assisted dual-anchoring activation (ICDA): a suitable preorganization for electrophilic halocyclization
Halocyclization reaction represents one of the most common methodologies for the synthesis of heterocyclic molecules. Many...
Protein painting for structural and binding sites analysis via intracellular lysine reactivity profiling with o-phthalaldehyde
The three-dimensional structure and the molecular interaction of proteins determine their roles in many cellular processes...
Non-invasive Diagnosis of Bacterial and Non-Bacterial Inflammations Using a Dual-Enzyme-Responsive Fluorescent Indicator
Bacterial infections, as the second leading cause of global death, are commonly treated with antibiotics. However, the imp...
Restraining the shuttle effect of polyiodide and modulating the deposition of zinc ions to enhance the cycle lifespan of aqueous Zn-I 2 battery
The boom of aqueous Zn-based energy storage devices, such as zinc-iodine (Zn-I2) batteries, is quite suitable for safe and...
Combining Geometric Constraint and Redox Non-Innocence within an Ambiphilic PBiP Pincer Ligand
The synthesis of the first pincer ligand featuring a strictly T-shaped group 15 element and its coordination behaviour tow...