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SynAsk: Unleashing the Power of Large Language Models in Organic Synthesis
The field of natural language processing (NLP) has witnessed a transformative shift with the emergence of large language m...
Reactivity of Metal Hydrides with CO2: Going Beyond Formate with a High-Valent Cationic Pentahydride Mo(VI) Complex
The cationic molybdenum pentahydride complex [MoH5(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) is shown to undergo t...
Strongly Photoluminescent and Radioluminescent Copper(I) Iodide Hybrid Materials Made of Coordinated Ionic Chains
Scintillation-based X-ray detection has been widely used in various fields from medical diagnostics to security. In this s...
Structural Characterization of Surface Immobilized Platinum Hydrides by Sensitivity-Enhanced 195Pt Solid State NMR Spectroscopy and DFT Calculations
Supported single-site platinum hydride compounds are promising heterogeneous catalysts for organic transformations. Few me...
Effective Design Strategy for Thermally Activated Delayed Fluorescence Emitters with Aggregation-Induced emission to Enable Sky-blue OLEDs Achieving EQE Nearly 30%
Pure organic thermally activated delayed fluorescence (TADF) materials hold great promise for efficient organic light-emit...
Enantioselective Nickel-Catalyzed Electrochemical Reductive Conjugate Alkenylation of α,β-Unsaturated Ketones
Catalytic electrochemical asymmetric catalysis starting to emerg as a promising strategy for the synthesis of chiral compo...
Aluminium porphyrins catalyse the hydrogenation of CO2 withH2
Boron-based frustrated Lewis pairs (FLPs) have become well-established catalysts for the hydrogenation of a wide range of ...
Tandem Rh(II)-catalyzed 1,3-acyloxy migration/intermolecular [2+2] cycloaddition of electronically deficient propargylic esters with alkenes and alkynes
Transition metal-catalyzed 1,3-acyloxy migration of propargylic esters represents one of the most straightforward routes t...
Copper depletion-induced tumor cuproptosis
Copper homeostasis is crucial for cells, especially for rapidly proliferating cancerous cells. Copper imbalance-induced ce...
An Ultra-fast Reaction Process for Recycling Lithium Ion Batteries via Galvanic Cell Interaction
The efficient realization of closed-loop process is an ultimate goal for reusing the retired lithium-ion batteries (LIBs),...
Reconstructing phase of vanadium oxides enables redox-catalysis manipulated reversible sulfur conversion for stable Zn-S batteries
The naturally sluggish redox kinetics and limited utilization associated with the sulfur conversion in Zn/S electrochemist...
6,6'-Biindeno[1,2-b]fluorene: an open-shell indenofluorene dimer
Nakano et al. reported that the antiaromatic indenofluorene (IF) isomers are diradicaloid molecules having varying degrees...
Sequence-defined Phosphoestamers for Selective Inhibition of the KRASG12D/RAF1 Interaction
RAS proteins are the most frequently mutated in cancer, yet they have proved extremely difficult to target for drug discov...
Ultra-long cycle sodium ion batteries enabled by glutaric anhydride additive
For sodium-ion batteries, solving the pain point of short cycle life is the key to large-scale promotion for the industry,...
Donor-free 9,10-dihydro-9,10-dialuminaanthracenes
Despite their promising potential, e.g., as ditopic, cooperatively binding Lewis acids, 9,10-dihydro-9,10-dialuminaanthrac...
Enhanced Electrocatalytic Nitrate-to-Ammonia Performance from Mott-Schottky Design to Induce Electron Redistribution
Constructing highly efficient electrocatalysts via interface manipulation and structural design to facilitate rapid electr...
Tunable Synthesis of Heteroleptic Zirconium-Based Porous Coordination Cages
Zirconium-based porous coordination cages have been widely studied and have shown to be potentially useful for many applic...
Selective Oxidation of Active Site Aromatic Residues in Engineered Cu Proteins
Recent studies have revealed critical roles for the local environments surrounding metallocofactors, such as the newly ide...
Archaerhodopsin 3 is an Ideal Template for the Engineering of Highly Fluorescent Optogenetic Reporters
We are grateful to the reviewers for their globally positive evaluation and the very constructive criticism and suggestion...
Why do Some Metal Ions Spontaneously Form Nanoparticles in Water Microdroplets: Disentangling the Contributions of Air–Water Interface and Bulk Redox Chemistry
Water microdroplets containing 100 µM HAuCl4 have been shown to reduce gold ions into gold nanoparticles spontaneousl...
Dithienoarsinines: Stable and Planer π-Extended Arsabenzenes
Stable planar dithienoarsinines were synthesized and structurally characterized. These compounds exhibit monomeric structu...
Switchable Magnetic Resonance Imaging Nanoplatform for in Situ MicroRNA Imaging
Aberrant microRNA (miRNA) expression is associated with various types of carcinogenesis, making miRNA a promising candidat...
Unlocking Regioselectivity: Steric Effects and Conformational Constraints of Lewis Bases in Alkyllithium-Initiated Butadiene Polymerization
In nonpolar solvents, alkyllithium-initiated 1,3-butadiene polymerization exhibits high 1,4-selectivity, which shifts towa...
Main-chain stiff-stilbene photoswitches in solution, in bulk, and at surfaces
Molecular photoswitches have been incorporated into polymer backbones to control the macromolecular conformations by struc...
Monitoring Electrophilic Intermediates in Reactions of Thiols in Aqueous Solution Directly With19F NMR
Mechanistic studies of thiol reactivity can be challenging because electrophilic reaction intermediates, such as sulfenic ...
Biosynthesis of a bacterial meroterpenoid reveals a non-canonical class II terpene synthase
Meroterpenoids are hybrid natural products that arise from the integration of terpenoid and non-terpenoid biosynthetic pat...
Chemical Protein Synthesis Combined with Protein Cell Delivery Reveals New Insights on the Maturation Process of SUMO2
The Small Ubiquitin-like Modifier (SUMO) is a crucial post-translational modifier of proteins, playing a key role in vario...
Facile Construction of Polyoxometalate-Polymer Hybrid Nanoparticles with pH/Redox Dual-Responsiveness.
Responsive nanomaterials have emerged as promising candidates for advanced drug delivery systems (DDSs), offering the pote...
Spin State Modulation and Kinetic Control of Thermal Contraction in a [Fe2Co2] Discrete Prussian Blue Analogue
Stimuli-responsive switchable molecules represent an important category of magnetic materials with significant potential f...
TcESTIME: predicting high-temperature hydrogen-based superconductors
Superconductivity can be considered among the most exciting discoveries in material science of the XXth century. However, ...
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