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Difluorenoheteroles: Topological Control of π Conjugation in Diradicaloids and Mixed-Valence Radical Ions
Two families of difluorenoheterole diradicaloids were synthesized, featuring isomeric ring systems with distinct conjugati...
Helically Twisted Nanoribbons via Stereospecific Annulative π-Extension Reaction Employing [7]Helicene as a Molecular Wrench
Over the past decade, significant progress has been made in synthesizing atomically precise carbon nanostructures, particu...
Maleimide Functionalized Polycaprolactone Micelles for Glutathione Quenching and Doxorubicin Delivery
High glutathione production is known to be one of the defense mechanisms by which many cancer cells survive elevated oxida...
Synthesis and Biological Evaluation of Cleistocaltone A, an Inhibitor of Respiratory Syncytial Virus (RSV)
The first chemical synthesis of the phloroglucinol meroterpenoid cleistocaltone A (1) is presented. This compund, previous...
Step-induced double-row pattern of interfacial water on rutile TiO2(110) at electrochemical conditions
Metal oxides are promising (photo)electrocatalysts for sustainable energy technologies due to their good activity and abun...
Elevating upconversion performance of a multiple resonance thermally activated delayed fluorescence emitter via an embedded azepine approach
Multiple resonance thermally activated delayed fluorescence (MR-TADF) emitters hold the promise of efficient organic light...
Computational Analysis of R-X Oxidative Addition to Pd Nanoparticles
Oxidative addition (OA) is a necessary step in mechanisms of widely used synthetic methodologies such as the Heck reaction...
Correction: Halogen-bonded charge-transfer co-crystal scintillators for high-resolution X-ray imaging
Correction for ‘Halogen-bonded charge-transfer co-crystal scintillators for high-resolution X-ray imaging’ by Yu-Hua Chen ...
Flexible hydrogen-bonded organic frameworks (HOFs): opportunities and challenges
Flexible behavior is one of the most fascinating features of hydrogen-bonded organic frameworks (HOFs), which represent an...
Efficient and stabilized molecular doping of hole-transporting materials driven by cyclic-anion strategy for perovskite solar cells
Bis(trifluoromethane)sulfonimide lithium salt (Li-TFSI) is commonly used as an effective dopant to improve the performance...
Electrochemical Recycling of Polymeric Materials
Polymeric materials play a pivotal role in our modern world, offering a diverse range of applications. However, they have ...
Engineering of bespoke photosensitiser-microbe interfaces for enhanced semi-artificial photosynthesis
Biohybrid systems for solar fuel production integrate artificial light-harvesting materials with biological catalysts such...
Intermedium aminophenol enables hectogram-scale synthesis of highly-bright red carbon quantum dots at ambient condition
Carbon quantum dots (C-dots) have developed into potential nanomaterials for lighting, catalysis and bioimaging because of...
Complex electrochemiluminescence patterns shaped by the hydrodynamics at a rotating bipolar electrode
Electrochemiluminescence (ECL) is a powerful analytical approach that enables the optical readout of electrochemical proce...
Acridine Photocatalysis Enables Tricomponent Direct Decarboxylative Amine Construction
Amines are centrally important motifs in medicinal chemistry and biochemistry, and indispensable intermediates and linchpi...
Site-Selective S-gem-Difluoroallylation of Unprotected Peptides with 3,3-Difluoroallyl Sulfonium Salts
Bench-stable 3,3-difluoroallyl sulfonium salts (DFASs), featuring tunable activity and their editable C-β and gem-difluoro...
Triboelectric Behaviour of Selected Zeolitic-Imidazolate Frameworks: Exploring Chemical, Morphological and Topological Influences
Tribo- and contact electrification remain poorly understood, baffling and discombobulating scientists for millennia. Despi...
Halo-perfluoroalkoxylation of gem-difluoroalkenes with short-lived alkali metal perfluoroalkoxides in triglyme
Alkali metal alkoxides play a pivotal role in nucleophilic alkoxylation reactions, offering pathways for the synthesis of ...
Facet-dependent synthesis of H2O2 from H2 and O2 over single-atom Pt modified Pd nanocrystal catalysts
Hydrogen peroxide (H2O2) is one of the most valuable clean energy with rapidly growing requirement in industry and living ...
Revisiting the Reaction Pathways for Phospholipid Hydrolysis Catalyzed by Phospholipase A2 with QM/MM Methods
Secreted phospholipase A2 (sPLA2) is a Ca2+-dependent, widely distributed enzyme superfamily in almost all mammalian tissu...
Increased CO2/N2 selectivity by stepwise fluorination in isoreticular ultramicroporous metal-organic frameworks
Exploration of porous adsorbents with high CO2/N2 selectivity is of great significance for reducing CO2 content in the atm...
Carboxylate ester-based electrolytes for Na-ion batteries
Sodium-ion batteries (SIBs) are promising technology for next-generation energy storage. However, their performance is lim...
Copper/Ruthenium Relay Catalysis Enables 1,6-Double Chiral Inductions with Stereodivergence
Dual catalysis strategy is an efficient and powerful tool to fulfill the stereodivergent synthesis of all stereoisomeric p...
Re-assessing viologens for modern bio-electrocatalysis
Viologens, 1,1′-disubstituted-4,4′-bipyridinium salts, are organic redox species that can be used in place of NADPH as med...
Selectively “Size-Excluding” Water Molecules to Enable Highly Reversible Zinc Metal Anode
Significant water-related side reactions hinder the development of highly safe, low-cost aqueous zinc metal batteries (AZM...
Efficient Cytosolic Delivery of Luminescent Lanthanide Bioprobes in Live Cells for Two-Photon Microscopy
Lanthanide(III) (Ln3+) complexes have desirable photophysical properties for optical bioimaging. However, despite their ad...
2D arrays of hollow carbon nanoboxes: outward contraction-induced hollowing mechanism in Fe−N−C catalysts
Maximizing the utilization efficiency of monatomic Fe sites in Fe−N−C catalysts poses a significant challenge for their co...
Facile synthesis of hydrazone-based zinc(II) complex for ferroptosis-augmented sonodynamic therapy
Sonodynamic therapy (SDT), as a novel non-invasive cancer treatment modality derived from photodynamic therapy (PDT), has ...