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Capillary electrophoresis mass spectrometry identifies new isomers of inositol pyrophosphates in mammalian tissues
Technical challenges have to date prevented a complete profiling of the levels of myo-inositol phosphates (InsPs) and pyro...
Multifaceted behavior of a doubly reduced arylborane in B–H-bond activation and hydroboration catalysis
Alkali-metal salts of 9,10-dimethyl-9,10-dihydro-9,10-diboraanthrancene (M2[DBA-Me2]; M+ = Li+, Na+, K+) activate the H–B ...
Electronic Structure Comparisons of Isostructural Early d- and f-Block Metal(III) Bis(cyclopentadienyl) Silanide Complexes
We report the synthesis of the U(III) bis(cyclopentadienyl) hypersilanide complex [U(Cp′′)2] (Cp′′ = ), together with isos...
Electrochemical Radical-Mediated Selective C(sp3)-S Bond Activation
Selective C(sp3)-S bond breaking and transformation remains a particularly important, yet challenging goal in synthetic ch...
Time and angle resolved photoemission spectroscopy (TR-ARPES) of TMDC monolayers and bilayers
Many unique properties in two-dimensional (2D) materials and their heterostructures rely on charge excitation, scattering,...
Polymeric Encapsulation of a Ruthenium(II) Polypyridyl Complex: From Synthesis to in vivo Studies against High-Grade Epithelial Ovarian Cancer
The in vitro and in vivo translation of metal-based cytotoxic drugs has proven to be a significant hurdle in their establi...
Crystal growth kinetics guided Cu aerogel for highly-efficient CO2 electrolysis to C2+ alcohols
To realize commercial CO2 electrochemical reduction to C2+ alcohols, the selectivity and production rate should be further...
Fluorescent Organometallic Dyads and Triads: Establishing spatial Relationships
FRET pairs involving up to three different Bodipy dyes are utilized to provide information on the assembly/disassembly of ...
Inherently Chiral Calixarenes by a Catalytic Enantioselective Desymmetrizing Cross-Dehydrogenative Coupling
Under the catalysis of PdBr2 and a chiral phosphoramidite ligand, the upper-rim mono (2-bromoaroyl)-substituted calix[4]ar...
Kinked structure and interchain van der Waals interaction of carbyne nanocrystals
Carbyne with the one-dimensional sp-hybridized carbon atoms is the third form of carbon following diamond and graphite. Al...
Dative B←N bonds based crystalline organic framework with permanent porosity for acetylene storage and separation
The utilization of dative B←N bonds for the creation of crystalline organic framework (BNOF) are receiving an increasingly...
Cu-catalyzed enantioselective decarboxylative cyanation via the synergistic merger of photocatalysis and electrochemistry
The development of efficient and straightforward method for decarboxylative coupling using common alkyl carboxylic acid is...
Regiodivergent Metal-Catalyzed B(4)- and C(1)-Selenylation of o-Carboranes
Regiodivergent transition metal-catalyzed B(4)- and C(1)-selenylation reactions of o-carboranes have been demonstrated. Na...
Thiol-sulfoxonium ylide photo-click reaction for bioconjugation
Visible-light-mediated methods were heavily studied as a useful tool for cysteine-selective bio-conjugation; however, many...
Angularly Fused Diaza-Dinaphthopyrenes: Regio-Selective Synthesis, Crystal Structures and Isomer-Dependent Mechanochromic Fluorescent Properties
We report a one-pot synthesis of a series of unprecedented angular-fused diaza-dinaphthopyrene isomers (1,8-DNPy, 1,6-DNPy...
Metal Complexes for Catalytic and Photocatalytic Reactions in Living Cells and Organisms
TThe development of organometallic catalysis has greatly expanded the synthetic chemist toolbox compared to that only expl...
Correction: Construction of isostructural hydrogen-bonded organic frameworks: limitations and possibilities of pore expansion
Correction for ‘Construction of isostructural hydrogen-bonded organic frameworks: limitations and possibilities of pore ex...
Correction: An exchange coupled meso–meso linked vanadyl porphyrin dimer for quantum information processing
Correction for ‘An exchange coupled meso–meso linked vanadyl porphyrin dimer for quantum information processing’ by Davide...
Tuning dynamic DNA- and peptide-driven self-assembly in DNA-peptide conjugates
DNA-peptide conjugates offer an opportunity to marry the benefits of both biomolecules, such as the high level of control ...
Back to the future of organolanthanide chemistry
At the dawn of the development of structural organometallic chemistry, soon after the discovery of ferrocene, the descript...
Turn-on fluorescent capsule for selective fluoride detection and water purification
It has been a long-standing challenge to develop organic molecular capsules for selective anion binding in water. Here, se...
Supramolecular multi-electron redox photosensitisers comprising a ring-shaped Re(I) tetranuclear complex and a polyoxometalate
Redox photosensitisers (PSs) play essential roles in various photocatalytic reactions. Herein, we synthesised new redox PS...
Transmitting Biomolecular Chirality into Carbon Nanodots: A Facile Approach to Acquire Chiral Light Emission at the Nanoscale
Since the observation of chirality at the nanoscale, the research focused towards the design and synthesis of optically ac...