Stephens, I. E. et al. 2022 roadmap on low temperature electrochemical CO2 reduction. J. Phys. Energy 4, 042003 (2022).

Article  CAS  Google Scholar 

Bushuyev, O. S. et al. What should we make with CO2 and how can we make it? Joule 2, 825–832 (2018).

Article  CAS  Google Scholar 

Chen, A. & Lin, B.-L. A simple framework for quantifying electrochemical CO2 fixation. Joule 2, 594–606 (2018).

Article  CAS  Google Scholar 

Kibria Nabil, S., McCoy, S. & Kibria, M. G. Comparative life cycle assessment of electrochemical upgrading of CO2 to fuels and feedstocks. Green Chem. 23, 867–880 (2021).

Article  CAS  Google Scholar 

Ross, M. B. et al. Designing materials for electrochemical carbon dioxide recycling. Nat. Catal. 2, 648–658 (2019).

Article  CAS  Google Scholar 

Birdja, Y. Y. et al. Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels. Nat. Energy 4, 732–745 (2019).

Article  CAS  Google Scholar 

Benson, E. E., Kubiak, C. P., Sathrum, A. J. & Smieja, J. M. Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels. Chem. Soc. Rev. 38, 89–99 (2009).

Article  CAS  PubMed  Google Scholar 

Takeda, H., Cometto, C., Ishitani, O. & Robert, M. Electrons, photons, protons and earth-abundant metal complexes for molecular catalysis of CO2 reduction. ACS Catal. 7, 70–88 (2017).

Article  CAS  Google Scholar 

Sun, L., Reddu, V., Fisher, A. C. & Wang, X. Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts. Energy Environ. Sci. 13, 374–403 (2020).

Article  CAS  Google Scholar 

Corbin, N., Zeng, J., Williams, K. & Manthiram, K. Heterogeneous molecular catalysts for electrocatalytic CO2 reduction. Nano Res. 12, 2093–2125 (2019).

Article  CAS  Google Scholar 

Weekes, D. M., Salvatore, D. A., Reyes, A., Huang, A. & Berlinguette, C. P. Electrolytic CO2 reduction in a flow cell. Acc. Chem. Res. 51, 910–918 (2018).

Article  CAS  PubMed  Google Scholar 

Liang, H.-Q. et al. Hydrophobic copper interfaces boost electroreduction of carbon dioxide to ethylene in water. ACS Catal. 11, 958–966 (2021).

Article  CAS  Google Scholar 

Xing, Z., Hu, L., Ripatti, D. S., Hu, X. & Feng, X. Enhancing carbon dioxide gas-diffusion electrolysis by creating a hydrophobic catalyst microenvironment. Nat. Commun. 12, 136 (2021).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Ren, S. et al. Molecular electrocatalysts can mediate fast, selective CO2 reduction in a flow cell. Science 365, 367–369 (2019).

Article  CAS  PubMed  Google Scholar 

Wang, M. et al. CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine. Nat. Commun. 10, 3602 (2019).

Article  PubMed  PubMed Central  Google Scholar 

Furuya, N. & Matsui, K. Electroreduction of carbon dioxide on gas-diffusion electrodes modified by metal phthalocyanines. J. Electroanal. Chem. Interfac. Chem. 271, 181–191 (1989).

Article  CAS  Google Scholar 

Jiang, Z. et al. Molecular catalyst with near 100% selectivity for CO2 reduction in acidic electrolytes. Adv. Energy Mater. 13, 2203603 (2022).

Article  Google Scholar 

Sun, L. et al. Cobalt quaterpyridine complexes for highly efficient heterogeneous CO2 reduction in aqueous media. Adv. Energy Mater. 12, 2202108 (2022).

Article  CAS  Google Scholar 

Siritanaratkul, B. et al. Zero-gap bipolar membrane electrolyzer for carbon dioxide reduction using acid-tolerant molecular electrocatalysts. J. Am. Chem. Soc. 144, 7551–7556 (2022).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Bemana, H., McKee, M. & Kornienko, N. Electrocatalysis with molecules and molecular assemblies within gas diffusion electrodes. Chem. Sci. 14, 13696–13712 (2023).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Leung, J. J. et al. Solar-driven reduction of aqueous CO2 with a cobalt bis(terpyridine)-based photocathode. Nat. Catal. 2, 354–365 (2019).

Article  CAS  Google Scholar 

Pati, P. B. et al. Photocathode functionalized with a molecular cobalt catalyst for selective carbon dioxide reduction in water. Nat. Commun. 11, 3499 (2020).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Ahmed, M. E., Rana, A., Saha, R., Dey, S. & Dey, A. Homogeneous electrochemical reduction of CO2 to CO by a cobalt pyridine thiolate complex. Inorg. Chem. 59, 5292–5302 (2020).

Article  CAS  PubMed  Google Scholar 

Dey, S., Todorova, T. K., Fontecave, M. & Mougel, V. Electroreduction of CO2 to formate with low overpotential using cobalt pyridine thiolate complexes. Angew. Chem. Int. Ed. 59, 15726–15733 (2020).

Article  CAS  Google Scholar 

Elgrishi, N., Chambers, M. B. & Fontecave, M. Turning it off! Disfavouring hydrogen evolution to enhance selectivity for CO production during homogeneous CO2 reduction by cobalt-terpyridine complexes. Chem. Sci. 6, 2522–2531 (2015).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Tatikonda, R., Bhowmik, S., Rissanen, K., Haukka, M. & Cametti, M. Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands. Dalton Trans. 45, 12756–12762 (2016).

Article  CAS  PubMed  Google Scholar 

Baker, R. J., Colavita, P. E., Murphy, D. M., Platts, J. A. & Wallis, J. D. Fluorine-fluorine interactions in the solid state: an experimental and theoretical study. J. Phys. Chem. A 116, 1435–1444 (2012).

Article  CAS  PubMed  Google Scholar 

Ferreira, H., Conradie, M. M. & Conradie, J. Electrochemical and electronic properties of a series of substituted polypyridine ligands and their Co(II) complexes. Inorg. Chim. Acta 486, 26–35 (2019).

Article  CAS  Google Scholar 

Bredar, A. R. C., Chown, A. L., Burton, A. R. & Farnum, B. H. Electrochemical impedance spectroscopy of metal oxide electrodes for energy applications. ACS Appl. Energy Mater. 3, 66–98 (2020).

Article  CAS  Google Scholar 

Shen, J. et al. Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin. Nat. Commun. 6, 8177 (2015).

Article  PubMed  Google Scholar 

Ahmed, M. E. et al. Repurposing a bio-inspired NiFe hydrogenase model for CO2 reduction with selective production of methane as the unique C-based product. ACS Energy Lett. 5, 3837–3842 (2020).

Article  CAS  Google Scholar 

Boutin, E. & Robert, M. Molecular electrochemical reduction of CO2 beyond two electrons. Trends Chem. 3, 359–372 (2021).

Article  CAS  Google Scholar 

Furuya, N. & Koide, S. Electroreduction of carbon dioxide by metal phthalocyanines. Electrochim. Acta 36, 1309–1313 (1991).

Article  CAS  Google Scholar 

Abdinejad, M. et al. Electrocatalytic reduction of CO2 to CH4 and CO in aqueous solution using pyridine-porphyrins immobilized onto carbon nanotubes. ACS Sustain. Chem. Eng. 8, 9549–9557 (2020).

Article  CAS  Google Scholar 

Dong, S.-T., Xu, C. & Lassalle-Kaiser, B. Multiple C-C bond formation upon electrocatalytic reduction of CO2 by an iron-based molecular macrocycle. Chem. Sci. https://doi.org/10.1039/D2SC04729B (2023).

Article