Nano‐synthesis, solid‐state structural characterization, and antimicrobial and anticancer assessment of new sulfafurazole azo dye‐based metal complexes for further pharmacological applications

Table S1. Data of thermal gravimetric analysis (TGA) of the metal complexes (1, 3, 4, and 5) with H2L

Table S2: The bond lengths and bond angles of H2L, complex 1 and 2

Table S3: The bond lengths and bond angles of complex 3, 4 and 5

Table S4: The energetic properties of the ligand (H2L) and its complexes 1-6

Table S5. Antimicrobial activities of H2L and its metal complexes (1-7)

Table S6. The in-vitro antitumor activity (IC50) of H2L and complexes 1-7 against HepG-2

Figure S1. FT-IR spectra of the Co(II), Ni(II), and Cd(II) complexes

Figure S2. XRD spectral patterns of Cr(III), Fe(III), Co(II), Ni(II), Cu(II), and Cd(II) complexes

Figure S3. TEM images of Cr(III) complex 1 (A), Fe(III) complex 3 (B), Co(II) complex 4 (C), and Ni(II) complex 5 (D)

Figure S4. Optimized molecular structure of complexes 2-6

Figure S5. HOMO and LUMO Optimized molecular structure of ligand and its metal complexes 1-6

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