Molecule-like synthesis of ligand-protected metal nanoclusters

Matus, M. F. & Häkkinen, H. Understanding ligand-protected noble metal nanoclusters at work. Nat. Rev. Mater. 8, 372–389 (2023).

Article  CAS  Google Scholar 

Jin, R., Zeng, C., Zhou, M. & Chen, Y. Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities. Chem. Rev. 116, 10346–10413 (2016).

Article  PubMed  CAS  Google Scholar 

Chakraborty, I. & Pradeep, T. Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles. Chem. Rev. 117, 8208–8271 (2017).

Article  PubMed  CAS  Google Scholar 

Zhu, M., Aikens, C. M., Hollander, F. J., Schatz, G. C. & Jin, R. Correlating the crystal structure of a thiol-protected Au25 cluster and optical properties. J. Am. Chem. Soc. 130, 5883–5885 (2008).

Article  PubMed  CAS  Google Scholar 

Walter, M. et al. A unified view of ligand-protected gold clusters as superatom complexes. Proc. Natl Acad. Sci. USA 105, 9157–9162 (2008).

Article  PubMed  PubMed Central  CAS  Google Scholar 

Abeyasinghe, N. et al. Enhanced emission from single isolated gold quantum dots investigated using two-photon excited fluorescence near-field scanning optical microscopy. J. Am. Chem. Soc. 138, 16299–16307 (2016).

Article  PubMed  CAS  Google Scholar 

Deng, H. et al. Bis-Schiff base linkage-triggered highly bright luminescence of gold nanoclusters in aqueous solution at the single-cluster level. Nat. Commun. 13, 3381 (2022).

Article  PubMed  PubMed Central  CAS  Google Scholar 

Yu, Y. et al. Identification of a highly luminescent Au22(SG)18 nanocluster. J. Am. Chem. Soc. 136, 1246–1249 (2014).

Article  PubMed  CAS  Google Scholar 

Shang, L., Dong, S. & Nienhaus, G. U. Ultra-small fluorescent metal nanoclusters: synthesis and biological applications. Nano Today 6, 401–418 (2011).

Article  CAS  Google Scholar 

Wang, T., Wang, D., Padelford, J. W., Jiang, J. & Wang, G. Near-infrared electrogenerated chemiluminescence from aqueous soluble lipoic acid Au nanoclusters. J. Am. Chem. Soc. 138, 6380–6383 (2016).

Article  PubMed  CAS  Google Scholar 

Chen, S. et al. Near infrared electrochemiluminescence of rod-shape 25-atom AuAg nanoclusters that is hundreds-fold stronger than that of Ru(bpy)3 standard. J. Am. Chem. Soc. 141, 9603–9609 (2019).

Article  PubMed  CAS  Google Scholar 

Antonello, S., Perera, N. V., Ruzzi, M., Gascón, J. A. & Maran, F. Interplay of charge state, lability, and magnetism in the molecule-like Au25(SR)18 cluster. J. Am. Chem. Soc. 135, 15585–15594 (2013).

Article  PubMed  CAS  Google Scholar 

Zhu, Y., Guo, J., Qiu, X., Zhao, S. & Tang, Z. Optical activity of chiral metal nanoclusters. Acc. Mater. Res. 2, 21–35 (2020).

Article  Google Scholar 

Knoppe, S. & Bürgi, T. Chirality in thiolate-protected gold clusters. Acc. Chem. Res. 47, 1318–1326 (2014).

Article  PubMed  CAS  Google Scholar 

Zhang, M.-M. et al. Alkynyl-stabilized superatomic silver clusters showing circularly polarized luminescence. J. Am. Chem. Soc. 143, 6048–6053 (2021).

Article  PubMed  CAS  Google Scholar 

Kwak, K. & Lee, D. Electrochemistry of atomically precise metal nanoclusters. Acc. Chem. Res. 52, 12–22 (2018).

Article  PubMed  Google Scholar 

Chen, S. et al. Gold nanoelectrodes of varied size: transition to molecule-like charging. Science 280, 2098–2101 (1998).

Article  PubMed  CAS  Google Scholar 

Du, Y., Sheng, H., Astruc, D. & Zhu, M. Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties. Chem. Rev. 120, 526–622 (2019).

Article  PubMed  Google Scholar 

Shang, L., Xu, J. & Nienhaus, G. U. Recent advances in synthesizing metal nanocluster-based nanocomposites for application in sensing, imaging and catalysis. Nano Today 28, 100767 (2019).

Article  Google Scholar 

Du, B. et al. Glomerular barrier behaves as an atomically precise bandpass filter in a sub-nanometre regime. Nat. Nanotechnol. 12, 1096–1102 (2017).

Article  PubMed  PubMed Central  CAS  Google Scholar 

Jiang, X. et al. Noninvasive monitoring of hepatic glutathione depletion through fluorescence imaging and blood testing. Sci. Adv. 7, eabd9847 (2021).

Article  PubMed  PubMed Central  CAS  Google Scholar 

Zhou, K., Cai, W., Tan, Y., Zhao, Z. & Liu, J. Highly controllable nanoassemblies of luminescent gold nanoparticles with abnormal disassembly-induced emission enhancement for in vivo imaging applications. Angew. Chem. Int. Ed. 61, e202212214 (2022).

Article  CAS  Google Scholar 

Zhang, H. et al. Bacteria photosensitized by intracellular gold nanoclusters for solar fuel production. Nat. Nanotechnol. 13, 900–905 (2018).

Article  PubMed  CAS  Google Scholar 

Wang, Y. et al. Insights into charge transfer at an atomically precise nanocluster/semiconductor interface. Angew. Chem. Int. Ed. 59, 7748–7754 (2020).

Article  CAS  Google Scholar 

Mathew, A. & Pradeep, T. Noble metal clusters: applications in energy, environment, and biology. Part. Part. Syst. Charact. 31, 1017–1053 (2014).

Article  CAS  Google Scholar 

Cao, M. et al. Porphyrinic silver cluster assembled material for simultaneous capture and photocatalysis of mustard-gas simulant. J. Am. Chem. Soc. 141, 14505–14509 (2019).

Article  PubMed  CAS  Google Scholar 

Kawawaki, T. et al. Creation of high-performance heterogeneous photocatalysts by controlling ligand desorption and particle size of gold nanocluster. Angew. Chem. Int. Ed. 60, 21340–21350 (2021).

Article  CAS  Google Scholar 

Jadzinsky, P. D., Calero, G., Ackerson, C. J., Bushnell, D. A. & Kornberg, R. D. Structure of a thiol monolayer-protected gold nanoparticle at 1.1 Å resolution. Science 318, 430–433 (2007).

Article  PubMed  CAS  Google Scholar 

Yang, H. et al. All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures. Nat. Commun. 4, 2422 (2013).

Article  PubMed  Google Scholar 

Heaven, M. W., Dass, A., White, P. S., Holt, K. M. & Murray, R. W. Crystal structure of the gold nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18]. J. Am. Chem. Soc. 130, 3754–3755 (2008).

Article  PubMed  CAS  Google Scholar 

Desireddy, A. et al. Ultrastable silver nanoparticles. Nature 501, 399–402 (2013).

Article  PubMed  CAS  Google Scholar 

Yuan, S.-F. et al. Rod-shaped silver supercluster unveiling strong electron coupling between substituent icosahedral units. J. Am. Chem. Soc. 143, 12261–12267 (2021).

Article  PubMed  CAS  Google Scholar 

Hosier, C. A. & Ackerson, C. J. Regiochemistry of thiolate for selenolate ligand exchange on gold clusters. J. Am. Chem. Soc. 141, 309–314 (2019).

Article  PubMed  CAS  Google Scholar 

Cai, X. et al. Reversible switching of catalytic activity by shuttling an atom into and out of gold nanoclusters. Angew. Chem. I

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