Geim, A. K. & Grigorieva, I. V. van der Waals heterostructures. Nature 499, 419–425 (2013).

Article  CAS  PubMed  Google Scholar 

Cao, Y. et al. Unconventional superconductivity in magic-angle graphene superlattices. Nature 556, 43–50 (2018).

Article  CAS  PubMed  Google Scholar 

Andrei, E. Y. & MacDonald, A. H. Graphene bilayers with a twist. Nat. Mater. 19, 1265–1275 (2020).

Article  CAS  PubMed  Google Scholar 

Wang, L. et al. Correlated electronic phases in twisted bilayer transition metal dichalcogenides. Nat. Mater. 19, 861–866 (2020).

Article  CAS  PubMed  Google Scholar 

Klein, D. R. et al. Electrical switching of a bistable moiré superconductor. Nat. Nanotechnol. 18, 331–335 (2023).

Article  CAS  PubMed  Google Scholar 

Lin, J.-X. et al. Spin–orbit-driven ferromagnetism at half moiré filling in magic-angle twisted bilayer graphene. Science 375, 437–441 (2022).

Article  CAS  PubMed  Google Scholar 

Frisenda, R. et al. Recent progress in the assembly of nanodevices and van der Waals heterostructures by deterministic placement of 2D materials. Chem. Soc. Rev. 47, 53–68 (2018).

Article  CAS  PubMed  Google Scholar 

Lau, C. N., Bockrath, M. W., Mak, K. F. & Zhang, F. Reproducibility in the fabrication and physics of moiré materials. Nature 602, 41–50 (2022).

Article  CAS  PubMed  Google Scholar 

Novoselov, K. S., Mishchenko, A., Carvalho, A. & Castro Neto, A. H. 2D materials and van der Waals heterostructures. Science 353, aac9439 (2016).

Article  CAS  PubMed  Google Scholar 

Low, T. et al. Tunable optical properties of multilayer black phosphorus thin films. Phys. Rev. B Condens. Matter 90, 075434 (2014).

Article  CAS  Google Scholar 

Li, L. et al. Direct observation of the layer-dependent electronic structure in phosphorene. Nat. Nanotechnol. 12, 21–25 (2017).

Article  PubMed  Google Scholar 

Qiu, D. Y., da Jornada, F. H. & Louie, S. G. Environmental screening effects in 2D materials: renormalization of the bandgap, electronic structure, and optical spectra of few-layer black phosphorus. Nano Lett. 17, 4706–4712 (2017).

Article  CAS  PubMed  Google Scholar 

Wilson, N. R. et al. Determination of band offsets, hybridization, and exciton binding in 2D semiconductor heterostructures. Sci. Adv. 3, e1601832 (2017).

Article  PubMed  PubMed Central  Google Scholar 

Jobst, J., Kautz, J., Geelen, D., Tromp, R. M. & van der Molen, S. J. Nanoscale measurements of unoccupied band dispersion in few-layer graphene. Nat. Commun. 6, 8926 (2015).

Article  CAS  PubMed  Google Scholar 

Li, H. et al. Imaging moiré flat bands in three-dimensional reconstructed WSe2/WS2 superlattices. Nat. Mater. 20, 945–950 (2021).

Article  CAS  PubMed  Google Scholar 

Leisgang, N. et al. Giant Stark splitting of an exciton in bilayer MoS2. Nat. Nanotechnol. 15, 901–907 (2020).

Article  CAS  PubMed  Google Scholar 

Tang, Y. et al. Tuning layer-hybridized moiré excitons by the quantum-confined Stark effect. Nat. Nanotechnol. 16, 52–57 (2021).

Article  CAS  PubMed  Google Scholar 

Klein, J. et al. Electric-field switchable second-harmonic generation in bilayer MoS2 by inversion symmetry breaking. Nano Lett. 17, 392–398 (2017).

Article  CAS  PubMed  Google Scholar 

Choi, J., Lane, C., Zhu, J.-X. & Crooker, S. A. Asymmetric magnetic proximity interactions in MoSe2/CrBr3 van der Waals heterostructures. Nat. Mater. 22, 305–310 (2022).

Article  PubMed  Google Scholar 

Soriano, D. & Lado, J. L. Exchange-bias controlled correlations in magnetically encapsulated twisted van der Waals dichalcogenides. J. Phys. D Appl. Phys. 53, 474001 (2020).

Article  CAS  Google Scholar 

Wang, Z., Li, R., Su, C. & Loh, K. P. Intercalated phases of transition metal dichalcogenides. SmartMat https://doi.org/10.1002/smm2.1013 (2020).

Chaves, A. et al. Bandgap engineering of two-dimensional semiconductor materials. npj 2D Mater. Appl. 4, 1–21 (2020).

Article  Google Scholar 

Huang, Q. et al. The mechanistic insights into the 2H-1T phase transition of MoS2 upon alkali metal intercalation: from the study of dynamic sodiation processes of MoS2 nanosheets. Adv. Mater.Interfaces 4, 1700171 (2017).

Article  Google Scholar 

Liu, K. et al. Evolution of interlayer coupling in twisted molybdenum disulfide bilayers. Nat. Commun. 5, 4966 (2014).

Article  CAS  PubMed  Google Scholar 

van der Zande, A. M. et al. Tailoring the electronic structure in bilayer molybdenum disulfide via interlayer twist. Nano Lett. 14, 3869–3875 (2014).

Article  PubMed  Google Scholar 

Debnath, R. et al. Tuning exciton complexes in twisted bilayer WSe2 at intermediate misorientation. Phys. Rev. B Condens. Matter 106, 125409 (2022).

Article  CAS  Google Scholar 

Wang, Y., Wang, Z., Yao, W., Liu, G.-B. & Yu, H. Interlayer coupling in commensurate and incommensurate bilayer structures of transition-metal dichalcogenides. Phys. Rev. B Condens. Matter 95, 115429 (2017).

Article  Google Scholar 

Zhang, Z. et al. Flat bands in twisted bilayer transition metal dichalcogenides. Nat. Phys. 16, 1093–1096 (2020).

Article  CAS  Google Scholar 

Shabani, S. et al. Deep moiré potentials in twisted transition metal dichalcogenide bilayers. Nat. Phys. 17, 720–725 (2021).

Article  CAS  Google Scholar 

Halbertal, D. et al. Moiré metrology of energy landscapes in van der Waals heterostructures. Nat. Commun. 12, 242 (2021).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Yoo, H. et al. Atomic and electronic reconstruction at the van der Waals interface in twisted bilayer graphene. Nat. Mater. 18, 448–453 (2019).

Article  CAS  PubMed  Google Scholar 

Weston, A. et al. Atomic reconstruction in twisted bilayers of transition metal dichalcogenides. Nat. Nanotechnol. 15, 592–597 (2020).

Article  CAS  PubMed  Google Scholar 

Sung, S. H. et al. Torsional periodic lattice distortions and diffraction of twisted 2D materials. Nat. Commun. 13, 7826 (2022).

Article  CAS  PubMed  PubMed Central  Google Scholar 

McGilly, L. J. et al. Visualization of moiré superlattices. Nat. Nanotechnol. 15, 580–584 (2020).

Article  CAS  PubMed  Google Scholar 

Kennes, D. M. et al. Moiré heterostructures as a condensed-matter quantum simulator. Nat. Phys. 17, 155–163 (2021).

Article  CAS  Google Scholar 

Van Winkle, M. et al. Rotational and dilational reconstruction in transition metal dichalcogenide moiré bilayers. Nat. Commun. 14, 2989 (2023).

Article  PubMed  PubMed Central  Google Scholar 

Naik, M. H., Kundu, S., Maity, I. & Jain, M. Origin and evolution of ultraflat bands in twisted bilayer transition metal dichalcogenides: realization of triangular quantum dots. Phys. Rev. B Condens. Matter 102, 075413 (2020).

Article  CAS  Google Scholar 

Enaldiev, V. V., Zólyomi, V., Yelgel, C., Magorrian, S. J. & Fal’ko, V. I. Stacking domains and dislocation networks in marginally twisted bilayers of transition metal dichalcogenides. Phys. Rev. Lett. 124, 206101 (2020).

Article  CAS  PubMed  Google Scholar 

Tang, H., Carr, S. & Kaxiras, E. Geometric origins of topological insulation in twisted layered semiconductors. Phys. Rev. B Condens. Matter 104, 155415 (2021).

Article  CAS  Google Scholar 

Linderälv, C., Rahm, J. M. & Erhart, P. High-throughput characterization of transition metal dichalcogenide alloys: thermodynamic stability and electronic band alignment. Chem. Mater. 34, 9364–9372 (2022).

Article  Google Scholar 

Zhang, K. et al. Spectroscopic signatures of interlayer coupling in Janus MoSSe/MoS2 heterostructures. ACS Nano 15, 14394–14403 (2021).

Article  CAS  PubMed  Google Scholar 

Hofmann, N. et al. Link between interlayer hybridization and ultrafast charge transfer in WS2-graphene heterostructures. 2D Mater. 10, 035025 (2023).

Article