ali abdalsalam ahmed Ministry of Education, Rusafa Second Directorate of Education, Baghdad, Iraq Aqeel mahdi jreo Abstract

Various standard methods have previously been used for the synthesis of nanoparticles that
produce unhealthy waste. They are also considered unsafe and expensive methods. An alternative
technology is needed to synthesize nanoparticles that consume less energy and are more
environmentally friendly. In this research, a CuO/TiO2 nanocomposite has been synthesized with a
mole ratio of 1.5:1, which produces good energy and no environmental pollution using an easy
and fast method (electrochemical). The morphology and structure of the nanocomposite were
examined using TEM, FESEM, AFM, and FTIR. The particle size of the CuO/TiO2
nanocomposites was found to range between 10.52 and 88.10 nm, while optical properties were
diagnosed using UV-visible spectroscopy since its measurements showed the amount of gap
energy (3.08 eV). The structure of the nanocomposite was demonstrated using X-ray diffraction
(XRD), where the mixed anatase and rutile phases were observed for TiO2, while the monoclinic
(tenorite) phase was observed for CuO. Additionally, dye-sensitized solar cells (DSSCs) have
been fabricated from CuO/TiO2 nanocomposite, which was synthesized by a new green method,
and pigments (methylene blue as a chemical dye and chlorophyll as a natural dye). These DSSCs
were characterized by their high ability to absorb ultraviolet energy, where the efficiency of
energy conversion ɳ of ITO-CuO/TiO2 was approximately 2.62 and 3.87% with chlorophyll (a
natural dye) and methylene blue (a chemical dye), respectively, where ɳ of ITO-CuO/TiO2 with
methylene blue is the best.

Section

Research Articles

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

Submission of a manuscript to the Journal will be taken to imply that:

The work is original and has not been previously published (except in the form of an abstract or a part of a published lecture, review or thesis). It is not being considered for publication elsewhere, and If accepted for publication, it will NOT be published commercially elsewhere in the same form, in any language, without the consent of Editor or Publisher.