Based on the ideas of coordination and design chemistry, we propose a new strategy to balance the energy and sensitivity conflict by using dual anions structure in the energetic complex compounds’ realm. Therefore, a novel solvent-free complex based on the pyridine-4-carbonhydrazide ligand. The [Ni(4-PDCA)2(NO3)2](HClO4) (ECCs-1) owned six-coordinated octahedral structure containing dual anions which was identified by IR, EA and single-crystal XRD. To best of our known, it is the first reported dual anions structure and exhibits high detonation performance (D = 6350m s−1 and P = 16.7 GPa), excellent insensitivity (IS = 40 J; FS = 360 N), and acceptable thermal stability (Td = 131.3 ℃).

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