International Energy Agency. CO2 emissions in 2022 (IEA, 2023).
Fisher, B. et al. in Climate Change 2007: Mitigation. Contribution of Working Group III to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change Ch. 3 (eds Metz, B., Davidson, O. R., Bosch, P. R., Dave, R. & Meyer, L. A.) 169–250 (Cambridge Univ. Press, 2007).
CO2.Earth. 2100 projections. CO2.Earth https://www.co2.earth/2100-projections (2024).
United Nations Framework Convention on Climate Change. The Paris Agreement. UNFCCC https://unfccc.int/process-and-meetings/the-paris-agreement/the-paris-agreement (2022).
United Nations Framework Convention on Climate Change. The Glasgow Climate Pact: key outcomes from COP26. UNFCCC https://unfccc.int/process-and-meetings/the-paris-agreement/the-glasgow-climate-pact-key-outcomes-from-cop26 (2021).
Intergovernmental Panel on Climate Change. Climate Change 2021: The Physical Science Basis. Contribution of Working Group I to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (Cambridge Univ. Press, 2023).
Pickering, B., Lombardi, F. & Pfenninger, S. Diversity of options to eliminate fossil fuels and reach carbon neutrality across the entire European energy system. Joule 6, 1253–1276 (2022).
Article CAS PubMed PubMed Central Google Scholar
Nesbitt, E. R. Using waste carbon feedstocks to produce chemicals. Ind. Biotechnol. 16, 147–163 (2020).
Hepburn, C. et al. The technological and economic prospects for CO2 utilization and removal. Nature 575, 87–97 (2019).
Article CAS PubMed Google Scholar
Centi, G. & Perathoner, S. in Handbook of Climate Change Mitigation and Adaptation (eds Lackner, M., Sajjadi, B. & Chen, W.-Y.) 1803–1852 (2022).
Barecka, M. H., Ager, J. W. & Lapkin, A. A. Carbon neutral manufacturing via on-site CO2 recycling. iScience 24, 102514 (2021).
Article CAS PubMed PubMed Central Google Scholar
Markewitz, P. et al. Worldwide innovations in the development of carbon capture technologies and the utilization of CO2. Energy Environ. Sci. 5, 7281–7305 (2012).
Drechsler, C. & Agar, D. W. Intensified integrated direct air capture — power-to-gas process based on H2O and CO2 from ambient air. Appl. Energy 273, 115076 (2020).
Barzagli, F., Giorgi, C., Mani, F. & Peruzzini, M. Screening study of different amine-based solutions as sorbents for direct CO2 capture from air. ACS Sustain. Chem. Eng. 8, 14013–14021 (2020).
Veselovskaya, J. V. et al. Direct CO2 capture from ambient air using K2CO3/Al2O3 composite sorbent. Int. J. Greenh. Gas Control 17, 332–340 (2013).
European Parliament. Circular economy: definition, importance and benefits. European Parliament https://www.europarl.europa.eu/news/en/headlines/economy/20151201STO05603/circular-economy-definition-importance-and-benefits (2023).
Kaiser, S., Gold, S. & Bringezu, S. Environmental and economic assessment of CO2-based value chains for a circular carbon use in consumer products. Resour. Conserv. Recycl. 184, 106422 (2022).
Khoo, H. H., Halim, I. & Handoko, A. D. LCA of electrochemical reduction of CO2 to ethylene. J. CO2 Util. 41, 101229 (2020).
Cheng, Y., Hou, P., Wang, X. & Kang, P. CO2 electrolysis system under industrially relevant conditions. Acc. Chem. Res. 55, 231–240 (2022).
Article CAS PubMed Google Scholar
Martindale, B. Electrifying start-up. Nat. Catal. 4, 924–925 (2021).
Masel, R. I. et al. An industrial perspective on catalysts for low-temperature CO2 electrolysis. Nat. Nanotechnol. 16, 118–128 (2021).
Article CAS PubMed Google Scholar
CERT Systems. Essential chemicals without fossil fuels. CERT https://co2cert.com/ (2024).
eChemicles. Electrolysis for a better tomorrow! eChemicles https://echemicles.com/ (2024).
Dioxycle. Technology. Dioxycle https://dioxycle.com/#technology (2024).
Zhang, Z. et al. Membrane electrode assembly for electrocatalytic CO2 reduction: principle and application. Angew. Chem. Int. Ed. 62, e202302789 (2023).
Nguyen, T. N. & Dinh, C. T. Gas diffusion electrode design for electrochemical carbon dioxide reduction. Chem. Soc. Rev. 49, 7488–7504 (2020).
Article CAS PubMed Google Scholar
Ozden, A. et al. Carbon-efficient carbon dioxide electrolysers. Nat. Sustain. 5, 563–573 (2022).
Park, J. et al. Strategies for CO2 electroreduction in cation exchange membrane electrode assembly. Chem. Eng. J. 453, 139826 (2023).
Ma, M., Kim, S., Chorkendorff, I. & Seger, B. Role of ion-selective membranes in the carbon balance for CO2 electroreduction via gas diffusion electrode reactor designs. Chem. Sci. 11, 8854–8861 (2020).
Article CAS PubMed PubMed Central Google Scholar
Wren, J. C. et al. Design of an electrochemical cell making syngas (CO + H2) from CO2 and H2O reduction at room temperature. J. Electrochem. Soc. 155, B42 (2007).
Huang, J. E. et al. CO2 electrolysis to multicarbon products in strong acid. Science 372, 1074–1078 (2021).
Article CAS PubMed Google Scholar
Noh, S., Jeon, J. Y., Adhikari, S., Kim, Y. S. & Bae, C. Molecular engineering of hydroxide conducting polymers for anion exchange membranes in electrochemical energy conversion technology. Acc. Chem. Res. 52, 2745–2755 (2019).
Article CAS PubMed Google Scholar
Vermaas, D. A. & Smith, W. A. Synergistic electrochemical CO2 reduction and water oxidation with a bipolar membrane. ACS Energy Lett. 1, 1143–1148 (2016).
Salvatore, D. A. et al. Electrolysis of gaseous CO2 to CO in a flow cell with a bipolar membrane. ACS Energy Lett. 3, 149–154 (2018).
Stephens, I. E. L. et al. Roadmap on low temperature electrochemical CO2 reduction. J. Phys. Energy 4, 042003 (2022).
Wakerley, D. et al. Gas diffusion electrodes, reactor designs and key metrics of low-temperature CO2 electrolysers. Nat. Energy 7, 130–143 (2022).
Verma, S., Lu, X., Ma, S., Masel, R. I. & Kenis, P. J. A. The effect of electrolyte composition on the electroreduction of CO2 to CO on Ag based gas diffusion electrodes. Phys. Chem. Chem. Phys. 18, 7075–7084 (2016).
Article CAS PubMed Google Scholar
Verma, S. et al. Insights into the low overpotential electroreduction of CO2 to CO on a supported gold catalyst in an alkaline flow electrolyzer. ACS Energy Lett. 3, 193–198 (2018).
Larrazábal, G. O. et al. Analysis of mass flows and membrane cross-over in CO2 reduction at high current densities in an MEA-type electrolyzer. ACS Appl. Mater. Interfaces 11, 41281–41288 (2019).
Rabinowitz, J. A. & Kanan, M. W. The future of low-temperature carbon dioxide electrolysis depends on solving one basic problem. Nat. Commun. 11, 1–3 (2020).
Fan, M. et al. Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis. Nat. Catal. 6, 763–772 (2023).
Xie, Y. et al. High carbon utilization in CO2 reduction to multi-carbon products in acidic media. Nat. Catal. 5, 564–570 (2022).
Li, H. et al. Tailoring acidic microenvironments for carbon-efficient CO2 electrolysis over a Ni–N–C catalyst in a membrane electrode assembly electrolyzer. Energy Environ. Sci. 16, 1502–1510 (2023).
Li, L., Liu, Z., Yu, X. & Zhong, M. Achieving high single-pass carbon conversion efficiencies in durable CO2 electroreduction in strong acids via electrode structure engineering. Angew. Chem. Int. Ed. 62, e202300226 (2023).
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