An FeCl3-catalyzed oxidative condensation of NH-1,2,3-triazoles and aryl methyl ketones (or acetophenones) and DMF (N,N-dimethylformamide) for the synthesis of β-(1,2,3-triazolyl)-ketones was developed. DMF serves as one carbon source, and the resulting products display diverse reaction selectivity, highlighting the existence of distinct approaches.

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