Herein we report on the preparation, spectroscopic and thermal characterization, structural study, and magnetic investigation of a new heterobimetallic coordination polymer (CP) of formula n(1) [Hbpca = bis(2-pyridylcarbonyl)amide], which was isolated through the fixation of aerial carbon dioxide by the preformed [Cu(bpca)]+ complex in basic water/dmso solvent mixtures. Compound 1 is made up of neutral heterobimetallic zigzag chains growing parallel to the crystallographic c axis where carbonate, bicarbonate, and bpca anions act as bridges with regular alternating of a pair of [Cu(bpca)]+ units and one [Na(H2O)2]+ fragment. The two crystallographically independent copper(II) ions (Cu1 and Cu2) are five-coordinate in somewhat distorted square pyramidal surroundings with three nitrogen atoms from the bpca ligand and either one bicarbonate-oxygen (Cu1) or a carbonate-oxygen (Cu2) in the basal plane and a shared carbonate-oxygen atom (Cu1 and Cu2) in the apical position. Each sodium(I) ion is also five-coordinate in a distorted trigonal bipyramidal environment, with two oxygen atoms from a bpca ligand and a water molecule building the trigonal plane and a bicarbonate-oxygen and another water molecule in the axial sites. The intrachain copper-copper separation across the bridging carbonate is 4.109(1) Å. The cryomagnetic study of 1 reveals the occurrence of weak ferromagnetic interaction between the copper(II) ions through the bridging carbonate [J = + 0.17(4) cm-1, the spin Hamiltonian being defined as H = -JSCu1.SCu2]. Density functional theory (DFT) calculations on the [2(µ-CO3)] fragment of 1 in the gas phase and solid state were used to estimate the magnetic coupling constant (J = + 0.42 cm-1) and to describe the electronic structure and magnetic topology of the system.

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