Electrochemically induced sulfonylation of alkenes with disulfides as the starting reagents was developed. This transformation is a quite rare example of disulfides usage as S-partners in electrochemical C-S coupling. In some cases, disulfides are inert in electrochemical coupling and their formation in reactions starting from thiols (their synthetic precursors) turns out to be a dead end pathway. In the discovered process, exclusively vinyl sulfones are formed, which is surprising. Previously, in the reactions involving disulfides, only sulfenylation took place resulting in sulfides, which could be transformed into the corresponding sulfones only through oxygenation with mCBPA or other similar oxygen donors. The developed reaction is carried out under constant current conditions in an experimentally convenient undivided electrochemical cell equipped with a platinum anode and a stainless steel cathode. KI acts in this process as a supporting electrolyte and redox catalyst, which made possible formation of sulfonylating species from the starting disulfides. Taking into account the results of control experiments, CV study, and literature data, we proposed that both radical and ionic pathways could be involved in the formation of the desired products.

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