Dalko, P. I. & Moisan, L. In the golden age of organocatalysis. Angew. Chem. Int. Ed. 43, 5138–5175 (2004).
Bornscheuer, U. T. et al. Engineering the third wave of biocatalysis. Nature 485, 185–194 (2012).
Article CAS PubMed Google Scholar
Hsieh, D. et al. Observation of unconventional quantum spin textures in topological insulators. Science 323, 919–922 (2009).
Article CAS PubMed Google Scholar
Hendry, E. et al. Ultrasensitive detection and characterization of biomolecules using superchiral fields. Nat. Nanotechnol. 5, 783–787 (2010).
Article CAS PubMed Google Scholar
Tu, H.-F., Yang, P., Lin, Z.-H., Zheng, C. & You, S.-L. Time-dependent enantiodivergent synthesis via sequential kinetic resolution. Nat. Chem. 12, 838–844 (2020).
Article CAS PubMed Google Scholar
Yeom, J. et al. Chiromagnetic nanoparticles and gels. Science 359, 309–314 (2018).
Article CAS PubMed Google Scholar
Tang, Y. & Cohen Adam, E. Enhanced enantioselectivity in excitation of chiral molecules by superchiral light. Science 332, 333–336 (2011).
Article CAS PubMed Google Scholar
Banerjee-Ghosh, K. et al. Separation of enantiomers by their enantiospecific interaction with achiral magnetic substrates. Science 360, 1331–1334 (2018).
Article CAS PubMed Google Scholar
Kumar, J. et al. Detection of amyloid fibrils in Parkinson’s disease using plasmonic chirality. Proc. Natl Acad. Sci. USA 115, 3225–3230 (2018).
Article CAS PubMed PubMed Central Google Scholar
Steendam, R. R. E. et al. Emergence of single-molecular chirality from achiral reactants. Nat. Commun. 5, 5543 (2014).
Article CAS PubMed Google Scholar
Gohler, B. et al. Spin selectivity in electron transmission through self-assembled monolayers of double-stranded DNA. Science 331, 894–897 (2011).
Article CAS PubMed Google Scholar
Naaman, R., Paltiel, Y. & Waldeck, D. H. Chiral molecules and the electron spin. Nat. Rev. Chem. 3, 250–260 (2019).
Kim, Y. H. et al. Chiral-induced spin selectivity enables a room-temperature spin light-emitting diode. Science 371, 1129–1133 (2021).
Article CAS PubMed Google Scholar
Naaman, R., Paltiel, Y. & Waldeck, D. H. Chiral molecules and the spin selectivity effect. J. Phys. Chem. Lett. 11, 3660–3666 (2020).
Article CAS PubMed PubMed Central Google Scholar
Aragones, A. C. et al. Measuring the spin-polarization power of a single chiral molecule. Small 13, 1602519 (2017).
Naaman, R. & Waldeck, D. H. Spintronics and chirality: spin selectivity in electron transport through chiral molecules. Annu. Rev. Phys. Chem. 66, 263–281 (2015).
Article CAS PubMed Google Scholar
Al-Bustami, H. et al. Single nanoparticle magnetic spin memristor. Small 14, 1801249 (2018).
Brandt, J. R., Salerno, F. & Fuchter, M. J. The added value of small-molecule chirality in technological applications. Nat. Rev. Chem. 1, 0045 (2017).
Michaeli, K., Kantor-Uriel, N., Naaman, R. & Waldeck, D. H. The electron’s spin and molecular chirality—how are they related and how do they affect life processes? Chem. Soc. Rev. 45, 6478–6487 (2016).
Article CAS PubMed Google Scholar
Alwan, S. & Dubi, Y. Spinterface origin for the chirality-induced spin-selectivity effect. J. Am. Chem. Soc. 143, 14235–14241 (2021).
Article CAS PubMed Google Scholar
Ghazaryan, A., Paltiel, Y. & Lemeshko, M. Analytic model of chiral-induced spin selectivity. J. Phys. Chem. C 124, 11716–11721 (2020).
Qi, D., Kenaan, A., Cui, D. & Song, J. Novel insights into the selection to electron’s spin of chiral structure. Nano Energy 52, 142–152 (2018).
Dubi, Y. Spinterface chirality-induced spin selectivity effect in bio-molecules. Chem. Sci. 13, 10878–10883 (2022).
Article CAS PubMed PubMed Central Google Scholar
Evers, F., Korytár, R., Tewari, S. & van Ruitenbeek, J. M. Advances and challenges in single-molecule electron transport. Rev. Mod. Phys. 92, 035001 (2020).
Xin, N. et al. Concepts in the design and engineering of single-molecule electronic devices. Nat. Rev. Phys. 1, 211–230 (2019).
Park, J. et al. Coulomb blockade and the Kondo effect in single-atom transistors. Nature 417, 722–725 (2002).
Article CAS PubMed Google Scholar
Bai, J. et al. Anti-resonance features of destructive quantum interference in single-molecule thiophene junctions achieved by electrochemical gating. Nat. Mater. 18, 364–369 (2019).
Article CAS PubMed Google Scholar
Winkelmann, C. B., Roch, N., Wernsdorfer, W., Bouchiat, V. & Balestro, F. Superconductivity in a single-C60 transistor. Nat. Phys. 5, 876–879 (2009).
Kim, W. Y. & Kim, K. S. Tuning molecular orbitals in molecular electronics and spintronics. Acc. Chem. Res. 43, 111–120 (2010).
Article CAS PubMed Google Scholar
Waldrop, M. M. The chips are down for Moore’s law. Nat. News 530, 144–147 (2016).
Li, Y., Yang, C. & Guo, X. Single-molecule electrical detection: a promising route toward the fundamental limits of chemistry and life science. Acc. Chem. Res. 53, 159–169 (2020).
Article CAS PubMed Google Scholar
Yang, C. et al. Single-molecule electrical spectroscopy of organocatalysis. Matter 4, 2874–2885 (2021).
Yang, C. et al. Unveiling the full reaction path of the Suzuki–Miyaura cross-coupling in a single-molecule junction. Nat. Nanotechnol. 16, 1214–1223 (2021).
Article CAS PubMed Google Scholar
Chen, H. et al. Electron-catalyzed dehydrogenation in a single-molecule junction. J. Am. Chem. Soc. 143, 8476–8487 (2021).
Article CAS PubMed Google Scholar
Aragones, A. C. et al. Electrostatic catalysis of a Diels–Alder reaction. Nature 531, 88–91 (2016).
Article CAS PubMed Google Scholar
Huang, G. & Li, X. Applications of Michael addition reaction in organic synthesis. Curr. Org. Synth. 14, 568–571 (2017).
Sibi, P. M. & Manyem, S. Enantioselective conjugate additions. Tetrahedron 56, 8033–8061 (2000).
Yang, C. et al. Electric field–catalyzed single-molecule Diels–Alder reaction dynamics. Sci. Adv. 7, eabf0689 (2021).
Article CAS PubMed PubMed Central Google Scholar
Gómez-Torres, E., Alonso, D. A., Gómez-Bengoa, E. & Nájera, C. Enantioselective synthesis of succinimides by Michael addition of 1,3-dicarbonyl compounds to maleimides catalyzed by a chiral bis(2-aminobenzimidazole) organocatalyst. Eur. J. Org. Chem. 2013, 1434–1440 (2013).
Gersten, J., Kaasbjerg, K. & Nitzan, A. Induced spin filtering in electron transmission through chiral molecular layers adsorbed on metals with strong spin–orbit coupling. J. Chem. Phys. 139, 114111 (2013).
Xie, Z. et al. Spin specific electron conduction through DNA oligomers. Nano Lett. 11, 4652–4655 (2011).
Article CAS PubMed Google Scholar
Kondou, K. et al. Chirality-induced magnetoresistance due to thermally driven spin polarization. J. Am. Chem. Soc. 144, 7302–7307 (2022).
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