Understanding ligand-protected noble metal nanoclusters at work

Tsukuda, T. & Häkkinen, H. (eds) Protected Metal Clusters: From Fundamentals to Applications Vol. 9 (Elsevier, 2015).

Häkkinen, H. The gold–sulfur interface at the nanoscale. Nat. Chem. 4, 443 (2012).

Article  Google Scholar 

Chakraborty, I. & Pradeep, T. Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles. Chem. Rev. 117, 8208–8271 (2017).

Article  CAS  Google Scholar 

Nasaruddin, R. R., Chen, T., Yan, N. & Xie, J. Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters. Coord. Chem. Rev. 368, 60–79 (2018).

Article  CAS  Google Scholar 

Kang, X., Li, Y., Zhu, M. & Jin, R. Atomically precise alloy nanoclusters: syntheses, structures, and properties. Chem. Soc. Rev. 49, 6443–6514 (2020).

Article  Google Scholar 

Du, Y., Sheng, H., Astruc, D. & Zhu, M. Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties. Chem. Rev. 120, 526–622 (2019).

Article  Google Scholar 

Fernando, A., Weerawardene, K. L. D. M., Karimova, N. V. & Aikens, C. M. Quantum mechanical studies of large metal, metal oxide, and metal chalcogenide nanoparticles and clusters. Chem. Rev. 115, 6112–6216 (2015).

Article  CAS  Google Scholar 

Matus, M. F. & Häkkinen, H. Atomically precise gold nanoclusters: towards an optimal biocompatible system from a theoretical–experimental strategy. Small 17, 2005499 (2021).

Article  CAS  Google Scholar 

Jin, R. Atomically precise metal nanoclusters: stable sizes and optical properties. Nanoscale 7, 1549–1565 (2015).

Article  CAS  Google Scholar 

Jin, R., Zeng, C., Zhou, M. & Chen, Y. Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities. Chem. Rev. 116, 10346–10413 (2016).

Article  CAS  Google Scholar 

Heinecke, C. L. et al. Structural and theoretical basis for ligand exchange on thiolate monolayer protected gold nanoclusters. J. Am. Chem. Soc. 134, 13316–13322 (2012).

Article  CAS  Google Scholar 

Ackerson, C. J., Jadzinsky, P. D., Jensen, G. J. & Kornberg, R. D. Rigid, specific, and discrete gold nanoparticle/antibody conjugates. J. Am. Chem. Soc. 128, 2635–2640 (2006).

Article  CAS  Google Scholar 

Salorinne, K. et al. Conformation and dynamics of the ligand shell of a water-soluble Au102 nanoparticle. Nat. Commun. 7, 10401 (2016).

Article  CAS  Google Scholar 

Pearson, R. M., Juettner, V. V. & Hong, S. Biomolecular corona on nanoparticles: a survey of recent literature and its implications in targeted drug delivery. Front. Chem. 2, 108 (2014).

Article  Google Scholar 

Cao, Y. et al. Reversible isomerization of metal nanoclusters induced by intermolecular interaction. Chem 7, 2227–2244 (2021).

Article  CAS  Google Scholar 

Liu, Y. et al. Golden carbon nanotube membrane for continuous flow catalysis. Ind. Eng. Chem. Res. 56, 2999–3007 (2017).

Article  CAS  Google Scholar 

Wu, Z. et al. Thiolate ligands as a double-edged sword for CO oxidation on CeO2 supported Au25(SCH2CH2Ph)18 nanoclusters. J. Am. Chem. Soc. 136, 6111–6122 (2014).

Article  CAS  Google Scholar 

Ma, Z., Wang, P., Xiong, L. & Pei, Y. Thiolate‐protected gold nanoclusters: structural prediction and the understandings of electronic stability from first principles simulations. Wiley Interdiscip. Rev. Comput. Mol. Sci. 7, e1315 (2017).

Article  Google Scholar 

Xie, Y.-P. et al. Silver nanoclusters: synthesis, structures and photoluminescence. Mater. Chem. Front. 4, 2205–2222 (2020).

Article  CAS  Google Scholar 

Baghdasaryan, A. & Bürgi, T. Copper nanoclusters: designed synthesis, structural diversity, and multiplatform applications. Nanoscale 13, 6283–6340 (2021).

Article  CAS  Google Scholar 

Akola, J., Walter, M., Whetten, R. L., Häkkinen, H. & Grönbeck, H. On the structure of thiolate-protected Au25. J. Am. Chem. Soc. 130, 3756–3757 (2008).

Article  CAS  Google Scholar 

Pei, Y., Gao, Y. & Zeng, X. C. Structural prediction of thiolate-protected Au38: a face-fused bi-icosahedral Au core. J. Am. Chem. Soc. 130, 7830–7832 (2008).

Article  CAS  Google Scholar 

Lopez-Acevedo, O., Tsunoyama, H., Tsukuda, T., Häkkinen, H. & Aikens, C. M. Chirality and electronic structure of the thiolate-protected Au38 nanocluster. J. Am. Chem. Soc. 132, 8210–8218 (2010).

Article  CAS  Google Scholar 

Vergara, S. et al. MicroED structure of Au146(p-MBA)57 at subatomic resolution reveals a twinned FCC cluster. J. Phys. Chem. Lett. 8, 5523–5530 (2017).

Article  CAS  Google Scholar 

Liu, C. et al. Observation of body‐centered cubic gold nanocluster. Angew. Chem. 127, 9964–9967 (2015).

Article  Google Scholar 

Huang, X. et al. Synthesis of hexagonal close-packed gold nanostructures. Nat. Commun. 2, 292 (2011).

Article  Google Scholar 

Zhu, M., Aikens, C. M., Hollander, F. J., Schatz, G. C. & Jin, R. Correlating the crystal structure of a thiol-protected Au25 cluster and optical properties. J. Am. Chem. Soc. 130, 5883–5885 (2008).

Article  CAS  Google Scholar 

Heaven, M. W., Dass, A., White, P. S., Holt, K. M. & Murray, R. W. Crystal structure of the gold nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18]. J. Am. Chem. Soc. 130, 3754–3755 (2008).

Article  CAS  Google Scholar 

Jadzinsky, P. D., Calero, G., Ackerson, C. J., Bushnell, D. A. & Kornberg, R. D. Structure of a thiol monolayer-protected gold nanoparticle at 1.1 Å resolution. Science 318, 430–433 (2007).

Article  CAS  Google Scholar 

Wei, X., Xu, C., Li, H., Kang, X. & Zhu, M. Fabrication of a family of atomically precise silver nanoclusters via dual-level kinetic control. Chem. Sci. 13, 5531–5538 (2022).

Article  CAS  Google Scholar 

Aikens, C. M. Electronic and geometric structure, optical properties, and excited state behavior in atomically precise thiolate-stabilized noble metal nanoclusters. Acc. Chem. Res. 51, 3065–3073 (2018).

Article  CAS  Google Scholar 

Chen, T. et al. Crystallization-induced emission enhancement: a novel fluorescent Au–Ag bimetallic nanocluster with precise atomic structure. Sci. Adv. 3, e1700956 (2017).

Article  Google Scholar 

Xie, X. et al. The origin of the photoluminescence enhancement of gold‐doped silver nanoclusters: the importance of relativistic effects and heteronuclear gold–silver bonds. Angew. Chem. Int. Ed. 57, 9965–9969 (2018).

Article  CAS  Google Scholar 

Krishnadas, K. R. et al. Metal–ligand interface in the chemical reactions of ligand-protected noble metal clusters. Langmuir 35, 11243–11254 (2018).

Article  Google Scholar 

Baksi, A. et al. Isomerism in monolayer protected silver cluster ions: an ion mobility–mass spectrometry approach. J. Phys. Chem. C 121, 13421–13427 (2017).

Article  CAS  Google Scholar 

Matus, M. F. et al. A topological isomer of the Au25(SR)18− nanocluster. Chem. Commun. 56, 8087–8090 (2020).

Article  CAS  Google Scholar 

Kalenius, E. et al. Experimental confirmation of a topological isomer of the ubiquitous Au25(SR)18 cluster in the gas phase. J. Am. Chem. Soc. 143, 1273–1277 (2021).

Article  CAS  Google Scholar 

Krishnadas, K. R. et al. Intercluster reactions between Au25(SR)18 and Ag44(SR)30. J. Am. Chem. Soc. 138, 140–148 (2016).

Article  CAS  Google Scholar 

Zhang, B., Chen, J., Cao, Y., Chai, O. J. H. & Xie, J. Ligand design in ligand‐protected gold nanoclusters. Small 17, 2004381 (2021).

Article  CAS  Google Scholar 

Qian, H. et al. Conversion of polydisperse Au nanoparticles into monodisperse Au25 nanorods and nanospheres. J. Phys. Chem. C 113, 17599–17603 (2009).

Article  CAS  Google Scholar 

Yuan, X., Goswami, N., Mathews, I., Yu, Y. & Xie, J. Enhancing stability through ligand-shell engineering: a case study with Au25(SR)18 nanoclusters. Nano Res. 8, 3488–3495 (2015).

Article  CAS  Google Scholar 

Song, Y. et al. Crystal structure of Au25(SePh)18 nanoclusters and insights into their electronic, optical and catalytic properties. Nanoscale 6, 13977–13985 (2014).

Article  CAS  Google Scholar 

Wan, X.-K., Wang, J.-Q., Nan, Z.-A. & Wang, Q.-M. Ligand effects in catalysis by atomically precise gold nanoclusters. Sci. Adv. 3, e1701823 (2017).

Article  Google Scholar 

Wu, Z. & Jin, R. On the ligand’s role in the fluorescence of gold nanoclusters. Nano Lett. 10, 2568–2573 (2010).

Article  CAS  Google Scholar 

Deng, G. et al. From symmetry breaking to unraveling the origin of the chirality of ligated Au13Cu2 nanoclusters. Angew. Chem. 130, 3479–3483 (2018).

Article  Google Scholar 

Hostetler, M. J., Green, S. J., Stokes, J. J. & Murray, R. W. Monolayers in three dimensions: synthesis and electrochemistry of ω-functionalized alkanethiolate-stabilized gold cluster compounds. J. Am. Chem. Soc. 118, 4212–4213 (1996).

Article  CAS  Google Scholar 

Hostetler, M. J., Templeton, A. C. & Murray, R. W. Dynamics of place-exchange reactions on monolayer-protected gold cluster molecules. Langmuir 15, 3782–3789 (1999).

Article  CAS 

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