Chen, P. et al. Single-molecule fluorescence imaging of nanocatalytic processes. Chem. Soc. Rev. 39, 4560–4570 (2010).
Vogt, E. T. C. & Weckhuysen, B. M. Fluid catalytic cracking: recent developments on the grand old lady of zeolite catalysis. Chem. Soc. Rev. 44, 7342–7370 (2015).
Wang, B. et al. From the molecule to the mole: improving heterogeneous copper catalyzed click chemistry using single molecule spectroscopy. Chem. Commun. 53, 328–331 (2017).
Chen, T. et al. Optical super-resolution imaging of surface reactions. Chem. Rev. 117, 7510–7537 (2017).
Wang, W. Imaging the chemical activity of single nanoparticles with optical microscopy. Chem. Soc. Rev. 47, 2485–2508 (2018).
Dong, B., Mansour, N., Huang, T.-X., Huang, W. & Fang, N. Single molecule fluorescence imaging of nanoconfinement in porous materials. Chem. Soc. Rev. 50, 6483–6506 (2021).
Eivgi, O. & Blum, S. A. Exploring chemistry with single-molecule and -particle fluorescence microscopy. Trends Chem. 4, 5–14 (2022).
Cordes, T. & Blum, S. A. Opportunities and challenges in single-molecule and single-particle fluorescence microscopy for mechanistic studies of chemical reactions. Nat. Chem. 5, 993–999 (2013).
Scaiano, J. C. & Lanterna, A. E. Is single-molecule fluorescence spectroscopy ready to join the organic chemistry toolkit? A test case involving click chemistry. J. Org. Chem. 82, 5011–5019 (2017).
Shaik, S., Mandal, D. & Ramanan, R. Oriented electric fields as future smart reagents in chemistry. Nat. Chem. 8, 1091–1098 (2016).
Shaik, S., Danovich, D., Joy, J., Wang, Z. & Stuyver, T. Electric-field mediated chemistry: uncovering and exploiting the potential of (oriented) electric fields to exert chemical catalysis and reaction control. J. Am. Chem. Soc. 142, 12551–12562 (2020).
Huang, X. & Li, T. Recent progress in the development of molecular-scale electronics based on photoswitchable molecules. J. Mater. Chem. C 8, 821–848 (2020).
Twilton, J. et al. The merger of transition metal and photocatalysis. Nat. Rev. Chem. 1, 0052 (2017).
Yan, M., Kawamata, Y. & Baran, P. S. Synthetic organic electrochemical methods since 2000: on the verge of a renaissance. Chem. Rev. 117, 13230–13319 (2017).
Rutledge, H. L. & Tezcan, F. A. Electron transfer in nitrogenase. Chem. Rev. 120, 5158–5193 (2020).
Joachim, C., Gimzewski, J. K. & Aviram, A. Electronics using hybrid-molecular and mono-molecular devices. Nature 408, 541–548 (2000).
Flood, A. H., Stoddart, J. F., Steuerman, D. W. & Heath, J. R. Whence molecular electronics? Science 306, 2055–2056 (2004).
Joachim, C. & Ratner, M. A. Molecular electronics: some views on transport junctions and beyond. Proc. Natl Acad. Sci. USA 102, 8801–8808 (2005).
Xiang, D., Wang, X., Jia, C., Lee, T. & Guo, X. Molecular-scale electronics: from concept to function. Chem. Rev. 116, 4318–4440 (2016).
Aragonès, A. C. et al. Electrostatic catalysis of a Diels–Alder reaction. Nature 531, 88–91 (2016).
Meng, L. et al. Side-group chemical gating via reversible optical and electric control in a single molecule transistor. Nat. Commun. 10, 1450 (2019).
Gehring, P., Thijssen, J. M. & van der Zant, H. S. J. Single-molecule quantum-transport phenomena in break junctions. Nat. Rev. Phys. 1, 381–396 (2019).
Chen, H. et al. Single-molecule charge transport through positively charged electrostatic anchors. J. Am. Chem. Soc. 143, 2886–2895 (2021).
Li, X. et al. Supramolecular systems and chemical reactions in single-molecule break junctions. Top. Curr. Chem. 375, 42 (2017).
Stone, I. et al. A single-molecule blueprint for synthesis. Nat. Rev. Chem. 5, 695–710 (2021).
Xie, X. et al. Single-molecule junction: a reliable platform for monitoring molecular physical and chemical processes. ACS Nano 16, 3476–3505 (2022).
Li, Y., Yang, C. & Guo, X. Single-molecule electrical detection: a promising route toward the fundamental limits of chemistry and life science. Acc. Chem. Res. 53, 159–169 (2020).
Cheng, Z. L. et al. In situ formation of highly conducting covalent Au–C contacts for single-molecule junctions. Nat. Nanotechnol. 6, 353–357 (2011).
Chen, W. et al. Highly conducting π-conjugated molecular junctions covalently bonded to gold electrodes. J. Am. Chem. Soc. 133, 17160–17163 (2011).
Hines, T. et al. Controlling formation of single-molecule junctions by electrochemical reduction of diazonium terminal groups. J. Am. Chem. Soc. 135, 3319–3322 (2013).
Starr, R. L. et al. Gold–carbon contacts from oxidative addition of aryl iodides. J. Am. Chem. Soc. 142, 7128–7133 (2020).
Doud, E. A. et al. In situ formation of N-heterocyclic carbene-bound single-molecule junctions. J. Am. Chem. Soc. 140, 8944–8949 (2018).
Zang, Y. et al. Electronically transparent Au–N bonds for molecular junctions. J. Am. Chem. Soc. 139, 14845–14848 (2017).
Lamberti, C., Zecchina, A., Groppo, E. & Bordiga, S. Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy. Chem. Soc. Rev. 39, 4951–5001 (2010).
Blasco, T. Insights into reaction mechanisms in heterogeneous catalysis revealed by in situ NMR spectroscopy. Chem. Soc. Rev. 39, 4685–4702 (2010).
Wasielewski, M. R. Photoinduced electron transfer in supramolecular systems for artificial photosynthesis. Chem. Rev. 92, 435–461 (1992).
Xu, W., Kong, J. S., Yeh, Y.-T. E. & Chen, P. Single-molecule nanocatalysis reveals heterogeneous reaction pathways and catalytic dynamics. Nat. Mater. 7, 992–996 (2008).
Xiao, Y. et al. Revealing kinetics of two-electron oxygen reduction reaction at single-molecule level. J. Am. Chem. Soc. 142, 13201–13209 (2020).
Zhou, X., Xu, W., Liu, G., Panda, D. & Chen, P. Size-dependent catalytic activity and dynamics of gold nanoparticles at the single-molecule Level. J. Am. Chem. Soc. 132, 138–146 (2010).
Liu, X. et al. Revealing the catalytic kinetics and dynamics of individual Pt atoms at the single-molecule level. Proc. Natl Acad. Sci. USA 119, e2114639119 (2022).
Rybina, A. et al. Distinguishing alternative reaction pathways by single-molecule fluorescence spectroscopy. Angew. Chem. Int. Ed. 52, 6322–6325 (2013).
Kim, D., Zhang, Z. & Xu, K. Spectrally resolved super-resolution microscopy unveils multipath reaction pathways of single spiropyran molecules. J. Am. Chem. Soc. 139, 9447–9450 (2017).
Ramsay, W. J., Bell, N. A. W., Qing, Y. & Bayley, H. Single-molecule observation of the intermediates in a catalytic cycle. J. Am. Chem. Soc. 140, 17538–17546 (2018).
Zaera, F. Probing liquid/solid interfaces at the molecular level. Chem. Rev. 112, 2920–2986 (2012).
Roeffaers, M. B. J. et al. Spatially resolved observation of crystal-face-dependent catalysis by single turnover counting. Nature 439, 572–575 (2006).
van Schrojenstein Lantman, E. M., Deckert-Gaudig, T., Mank, A. J. G., Deckert, V. & Weckhuysen, B. M. Catalytic processes monitored at the nanoscale with tip-enhanced Raman spectroscopy. Nat. Nanotechnol. 7, 583–586 (2012).
Choi, H.-K. et al. Single-molecule surface-enhanced Raman scattering as a probe of single-molecule surface reactions: promises and current challenges. Acc. Chem. Res. 52, 3008–3017 (2019).
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